Исследована кинетика и динамика образования зародышей новой фазы во внешнем электрическом поле E||[001] в сегнетоэлектрических релаксорах PbIn1/2Nb1/2O3-PbMg1/3 Nb2/3O3-xPbTiO3 (x=25 и 32%) и PbMg1/3Nb2/3O3-29PbTiO3. При комнатной температуре проведены совместные измерения оптического пропускания на разных длинах волн, а также скорости и затухания звука на разных частотах. Проведeн анализ характера изменений оптических и акустических свойств в различных электрических полях с целью выявления механизмов таких изменений в условиях фазового перехода. Уменьшение оптического пропускания со временем связано только с изменением размеров нанообластей в процессе фазового перехода. Hаблюдаемые акустические аномалии являются следствием фазового перехода и обусловлены увеличением жесткости решетки, вызванной большим пьезоэлектрическим эффектом в сегнетоэлектрической фазе. DOI: 10.21883/FTT.2017.10.44963.129
The kinetics of an induced phase transition in single-crystal relaxor solid solutions 33PbIn_1/2Nb_1/2O_3–35PbMg_1/3Nb_2/3O_3–32PbTiO_3 and PbMg_1/3Nb_2/3O_3–29PbTiO_3 under application of an electric field along three directions [001], [011], and [111] at room temperature is studied. Joint measurements of optical transmission at different wavelengths, dielectric properties, and attenuation of sound are carried out. It was found that, even in small fields ( E ~ 2 kV/cm) applied in the [011] and [111] directions, the maximum changes in all three characteristics as well as the coincidence of the time dependences of the optical transmission at different wavelengths of light occur in the same time interval. It is established that, in the same interval of fields along the [001] direction, the anomalies of the optical properties do not coincide in time with the anomalies of the acoustic and dielectric properties. The results obtained are explained by the induction of single-domain and multidomain phases.
The polarization kinetics in a transparent Pb(Mg_1/3Nb_2/3)O_3–23Pb(Zr_0.53Ti_0.47)O_3 ferroceramic is investigated in the electric fields of 0 < E < 6 kV/cm. The optical transmittance, dielectric, and acoustic properties of ferroceramics are measured at room temperature. The dielectric and acoustic characteristics are found to instantly switch even in fields below the coercive, due to the emergence of a partially ordered ferroelectric phase. Furthermore, the polarized phase arisen in the electric field is not completely stable.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.