Tribological characteristics of ultrahigh molecular weight polyethylene (UHMWPE) based compositions with graphite and molybdenum disulfide are studied under conditions of dry friction, boundary lubrication, and abrasive wear. It is shown that, under dry sliding friction, the wear rate of UHMWPE-graph ite and UHMWPE-MoS 2 polymer compositions is halved as compared to that of pure UHMWP, while their mechanical characteristics change only slightly. Under the conditions of abrasive wear, the wear resistance of these composites increases by 1.3-1.5 times. Concentrations of the fillers, which are optimum for improving the wear resistance, are determined. The supramolecular structure and the topography of worn surfaces of the UHMWPE compositions with various concentrations of the fillers are examined. A comparative analysis of the wear resistance of the composites under conditions of dry friction and lubrication is carried out. Mecha nisms of the wear of the UHMWPE-graphite and UHMWPE-MoS 2 polymer compositions under condi tions of dry sliding friction and abrasive wear are discussed.
In order to find an effective solid lubrication filler for the composites based on ultra-high molecular weight polyethylene, tribotechnical properties of UHMWPE and its blends with calcium stearate (С36Н70СаО4, CS) under dry friction, boundary lubrication and abrasion were studied. It is demonstrated that wear rate of UHMWPE-CS compositions under dry sliding friction decreases by more than 4 times as compared to pure UHMWPE while the mechanicals properties do not change substantially. Under abrasion conditions the wear rate of the stated composites rises with the increased content of the filler. The optimal filler weight fraction is determined in terms of ensuring maximum wear resistance. The wear mechanisms of UHMWPE-based polymer compounds with a solid lubrication filler under dry sliding friction conditions and abrasion are discussed.
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