В статье приведены результаты исследований оптических и электромагнитных свойств электрохромных нанокомпозиционных пленок WO3 , модифицированных оксидом графена (GO), полученных методом электрохимического осаждения ионов W+ и GO– из раствора перокси-вольфрамовой кислоты (ПВК) W2 O11 2-(GO). Реализован управляемый процесс электрохимического осаждения электрохромных пленок WO3 , который осуществлялся с помощью катодного осаждения, при котором задавались начальное и конечное значение потенциала электроосаждения –0,5 и –1,5 В, а также количество циклов.

Aqualitative and quantitative system of criteria for evaluating the universality of volatile metal corrosion inhibitors (VCIs) applied to agricultural production conditions was developed. The system of qualitative criteria for universalism includes: 1- an assessment of the effectiveness of corrosion inhibition of metals under the conditions of the action of corrosion-specific stimulants present in the vapor- gas phase separately or together; 2 - suppression of various types of local corrosion caused by them in the composition of a corrosive medium; 3 - suppression in specific conditions of general and local corrosion of contacting metallic structural materials of various nature; 4 - observance of acceptable specific characteristics of VCI: ecological, class-related hazards, influence on chemical oxygen consumption (COC) and biochemical oxygen demand for the biodegradation of substances by microorganisms (BOD5). The system of quantitative criteria for universalism of the VCIs includes quantitative parameters for all the proposed qualitative items. A simplified assessment, taking into account only a part of the criteria for characterizing partially universal inhibitors, is proposed to be applied to the conditions of agricultural production. The experimental data for the volatile inhibitor IFKhAN-114 are given as an example of the effectiveness of the proposed criteria. It was shown that IFKhAN-114 is a partially universal inhi-bitor.

Metals play a pivotal role in industry; their use constantly grows. It is virtually impossible to find an industrial field without the use of metals and their alloys. However, owing to the quality degradation of metal during the operational process, corrosion appears not only on its surface but also under a coating, which leads to its destruction. To avoid this, corrosion inhibitors are necessary. Organic compounds have been widely used as corrosion inhibitors. Many organic corrosion inhibitors have been developed nowadays. In the literature, organic compounds comprising N, O, S and P heteroatoms are described, which reduce corrosion rate. The organic compounds are adsorbed on the metal surface, forming a thin layer. Adsorption occurs either through electrostatic interaction or, in some cases, the formation of covalent bonds. The work aimed to study isothiuronic salts as corrosion inhibitors to evaluate their protective properties using the polarisation curves method. Objects of research were isothiuronic compounds containing two active centres separated by saturated and unsaturated carbon bonds (structures 1-3). In structures 4-7, one isothiuronic fragment has different propylene substituting groups. It has been previously shown that these compounds can act as effective brightening agents when applying nickel coatings. A model solution with a density of 1.12 g/cm3 was prepared to study the corrosion inhibitors. The corrosion inhibitor concentration was 400 mg/L. Studies have shown that the compounds with two isothiuronic moieties do not always exhibit improved properties for inhibiting metal degradation in a corrosive environment. In particular, they showed worsening of the inhibiting properties for samples made of steel 20 and identical properties for that made of steel 3.