The degree of influence of corrections was studied by the method of high-temperature radiography of alloys of Cu-Ni, Fe-Ni, Au-Ag, KCl-KBr systems on the reverse imaging chamber on the diffuse temperature scattering of X-rays and scattering by defects of the crystal lattice. The research of the concentration and temperature dependences of the mean squares of the values of static and dynamic displacements of hypothetical atoms on their equilibrium positions in the crystal lattice was carried out. The method of separating the values of root-mean-square (RMS) dynamic and static displacements of atoms was described. The article is based on the choice of objects and research method. Mathematical relations for determining the temperature dependence of the X-ray characteristic temperature and complete RMS dynamic and static displacements of hypothetical atoms from the position of their equilibrium in the lattice are presented. The formulas for finding the values of the correction for temperature diffuse scattering of X-rays and the formula for calculating the values of static displacements are given through the parameter of the crystal lattice of the solid solution and the solvent, as well as through the values of the elastic constants of the investigated alloys. Some of the results of the investigation are illustrated graphically, and others -analytically. The advantage of the Chipman-Paskin method for determining the X-ray characteristic temperature and the advantage of evaluating the values of static displacements by temperature changes of the lattice parameter of the solid solution and the solvent are proved.
In previous works on the ratio (θД – the characteristic temperature of Debye, was calculated according to the Lindemann formula; V – molar volume of hypothetical lattice atoms; γ is the Gruneisen parameter) for the group of dodecaborides (TbB12, DyB12, HoB12, ErB12, TuB12, LaB12, UB12) the average value of γ = 1.3 was determined. However, due to the ambiguity of the coefficient of proportionality in the Lindemann formula by definition θD, the authors selected an independent high-temperature X-ray method for determining the dependence θr (T). Taking into account the immutability of the structure and type of interatomic connection in the temperature interval of the search (293–973 K), the authors evaluated the value and temperature dependence of γ (T) of each dodecaboride separately. The results of the search showed that the value of γ for each given dodecaboride is different, but practically independent from temperature. For some dodecaborides, the parameter γ is about 2–3 units, and for others it is overestimated. The values of γ made it possible to estimate the magnitude of the implicit γβ and the explicit parts of the universal measure of anharmonicity of dodecaborides , where β – real coefficient of volumetric expansion of the crystalline lattice. Because (n – dimensionless coefficient of proportionality), then the temperature change n(T) is also determined.
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