The study of isoamylene oligomerization over a number of microporous zeolites
such as H–Y, H–MOR, H–Beta, H–ZSM-12, and H–ZSM-5 revealed that the isoamylene
conversion rate decreases in the following order: H–MOR > H–Y > H–Beta-40
>> H–ZSM-12 > H–ZSM-5. The maximum yields of isoamylene oligomers were
achieved by using H–MOR (85.0%), H–Y (80.1%), and H–Beta-40 (79.8%). The
predominant isoamylene oligomers are dimers regardless of the zeolite catalyst
used. The trimer yield reaches its highest when wide-pore zeolites like H–MOR,
H–Y, or H–Beta-40 are employed. An increase in the number of acid sites enhances
monomer conversion rate, oligomer yield, and oligomer molecular weight.
Conditions for producing isopentene dimers and trimers with the maximum possible
yield were determined.
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