The Ti3AlC2-, (Ti,Nb)3AlC2-and Ti2AlC-based materials turned out to be more resistant than Crofer JDA steel in oxidizing atmosphere as 1000 h long tests at 600• C have shown. But the amounts of oxygen absorbed by the materials during testing were different. The Ti2AlC-based material demonstrated the lowest oxygen uptake, (Ti,Nb)3AlC2-based absorbed a somewhat higher amount and the highest amount was absorbed by Ti3AlC2-based material. Scanning electron microscopy and the Auger study witnessed that amounts of oxygen in the MAX phases before the exposure in air were as well different: the approximate stoichiometries of the matrix phases of materials were Ti3.1−3.2AlC2−2.2, Ti1.9−4Nb0.06−0.1AlC1.6−2.2O0.1−1.2 and Ti2.3−3.6AlC1−1.9O0.2−0.6, respectively. The higher amount of oxygen present in the MAX phase structures may be the reason for higher resistance to oxidation during long-term heating in air at elevated temperature. The studied materials demonstrated high stabilities in hydrogen atmosphere as well. The bending strength of the Ti3AlC2-and (Ti,Nb)3AlC2-based materials after keeping at 600• C in air and hydrogen increased by 10-15%, but the highest absolute value of bending strength before and after being kept in air and hydrogen demonstrated the Ti2AlC-based material (about 590 MPa).
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