1,2-Indanedione — A winning ticket for developing fingermarks: A validation study

Levin‐Elad, Michal; Liptz, Yakir; Bar-Or, Karni L.; Almog, Joseph

doi:10.1016/j.forsciint.2016.12.007

Cited by 22 publications

(8 citation statements)

References 8 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…Moreover, occasionally, the thermally nonsensitive surface developed better fingerprints than the thermally sensitive surface. This result is consistent with the result of Levin-Elad et al (24). The results are summarized in "number of cases out of 10 trials" column in Table 3.…”

Section: Confirmation Of the Optimal Formulation Using Real Thermalsupporting

confidence: 92%

Latent Fingermark Development on Thermal Paper using 1,2‐Indanedione/Zinc and Polyvinylpyrrolidone,

Hong

Kim

2017

Journal of Forensic Sciences

View full text Add to dashboard Cite

Polyvinylpyrrolidone (PVP) has been used in combination with 1,2-indanedione (1,2-IND) and ZnCl (Zn) to develop latent fingermarks. The results show that the optimal ratio of 1,2-IND/Zn:PVP is 1.0:0.4 (the concentration of PVP is 8%) for developing fingermark. The developed formulation was tested on the surfaces of 12 kinds of thermal papers. The variation in the fingermark development efficiency was observed within the same and among different kinds of thermal papers. The fingermark development efficiency was mostly better on the thermally sensitive surface compared to the thermally nonsensitive surface. However, similar or even better development was observed from a few thermally nonsensitive surfaces. The present method has shown better efficiency compared to the three other proposed methods on the thermally sensitive surface. In contrast, the present method was proven not the best for the thermally nonsensitive surface.

show abstract

Section: Confirmation Of the Optimal Formulation Using Real Thermalsupporting

confidence: 92%

Latent Fingermark Development on Thermal Paper using 1,2‐Indanedione/Zinc and Polyvinylpyrrolidone,

Hong

Kim

2017

Journal of Forensic Sciences

View full text Add to dashboard Cite

show abstract

“…The reaction of 1,3-indandione 1 with hetarylcarbaldehydes is a convenient route to various compounds, which are of interest both from theoretical point of view and in the perspective of their application as photoswitches, [1] semiconductors and photosemiconductors, [2] sensors for anions, [3] precursors for the synthesis of drugs and dyes, and so forth. [4][5][6] Our systematic studies summarized in a recent review [7] showed that the molecules combining in their structure nitrogen-containing aromatic heterocycles and 1,3-diketones or cyclic chalcones are subject to a large variety of dynamic processes, including the formation and cleavage of hydrogen bonds, proton transfer, reversible Z/E isomerization, and tautomeric and rotameric transformations. The reaction of 1,3-indandione with aldehydes proceeds via the intermediate adducts 2, which either undergo dehydrogenation with the formation of the products of condensation 3 or react with the second molecule of 1 forming the 1:2 adducts 4 (Scheme 1).…”

Section: Introductionmentioning

confidence: 99%

Unusual spontaneous oxidation of 2,2′‐(quinolin‐2‐ylmethylene)bis(1H‐indene‐1,3(2H)‐dione): An experimental and theoretical study of the mechanism

Sigalov

Shainyan

2022

J of Physical Organic Chem

View full text Add to dashboard Cite

2‐Quinolinecarbaldehyde reacts with 1,3‐indandione to give 2‐[(3‐hydroxy‐1‐oxo‐1H‐inden‐2‐yl)(quinolin‐2‐yl)methylene]‐1H‐indene‐1,3(2H)‐dione, which is the first example of self‐oxidation of the Michael adducts of cycloalkanones with aldehydes. The structure of the product of oxidation is also proved by NMR and elemental analysis of its bromination product 2‐[(2‐bromo‐1,3‐dioxo‐2,3‐dihydro‐1H‐inden‐2‐yl)(1,3‐dioxo‐1,3‐dihydro‐2H‐inden‐2‐ylidene)‐methyl]quinolinium tribromide salt. The mechanism of this unusual reaction is studied experimentally and theoretically in comparison with that of a similar reaction with 2‐pyridinecarbaldehyde, which does not lead to self‐oxidation. The three‐step mechanism includes the formation of a pre‐reaction complex, which suffers proton transfer to the pyridinic nitrogen atom, and the hydride ion transfer to the protonated aldehyde. The transition states for the two reactions differ by the position on the reaction coordinate and the heights of the free energy barriers (~25 and ~4 kcal/mol), which allows to explain the observed different reactivity of the two similar hetaryl aldehydes.

show abstract

“…1,2-Indanedione (IND) is a dual fingerprint reagent that reacts with amino acids to produce both a visual pink colour as well as strong luminescence. IND, compared to ninhydrin and 1,8-diazafluoren-9one (DFO), provides superior results in terms of both the luminescence intensity and detection rates [1][2][3] .…”

Section: Introductionmentioning

confidence: 99%

Effect of carrier solvent in 1,2-indanedione formulation on the development of fingermarks on porous substrates

Zhao

Wang

et al. 2021

Forensic Science International

View full text Add to dashboard Cite

1,2-Indanedione — A winning ticket for developing fingermarks: A validation study

Cited by 22 publications

References 8 publications

Latent Fingermark Development on Thermal Paper using 1,2‐Indanedione/Zinc and Polyvinylpyrrolidone,

Latent Fingermark Development on Thermal Paper using 1,2‐Indanedione/Zinc and Polyvinylpyrrolidone,

Unusual spontaneous oxidation of 2,2′‐(quinolin‐2‐ylmethylene)bis(1H‐indene‐1,3(2H)‐dione): An experimental and theoretical study of the mechanism

Effect of carrier solvent in 1,2-indanedione formulation on the development of fingermarks on porous substrates

Contact Info

Product

Resources

About