1,5-Stereocontrol in tin(IV) halide promoted reactions of 2-alkoxy-1-(2-tributylstannylethylidene)cyclohexanes with aldehydes

Kumar, Poonam; Thomas, Eric J.; Tray, Daniel R.

doi:10.1016/j.tet.2007.03.070

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1,5‐Stereocontrol in Tin(IV) Halide Promoted Reactions of 2‐Alkoxy‐1‐(2‐tributylstannylethylidene)cyclohexanes with Aldehydes.

2007

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Cyclohexane derivatives Q 0040 1,5-Stereocontrol in Tin(IV) Halide Promoted Reactions of 2-Alkoxy-1-(2-tributylstannylethylidene)cyclohexanes with Aldehydes. -It is found that the title reactions proceed with excellent stereoselectivity giving (Z)-1,5-syn-products like (III) and (V). -(KUMAR, P.; THOMAS*, E. J.; TRAY, D.; Tetrahedron 63 (2007) 27, 6287-6295; Sch. Chem., Univ. Manchester, Manchester M13 9PL, UK; Eng.) -Jannicke 40-078

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