1-Methyl-4-ferrocenylmethyl-3,5-diphenylpyrazole: A versatile ligand for palladium(II) and platinum(II)

Platinum(II) and palladium(II) complexes with (N,N′) and (C,N,N′)− ligands derived from pyrazole as anticancer and antimalarial agents: Synthesis, characterization and in vitro activities

“…Few cyclopalladated complexes derived from pyrazole are known [37][38][39][40][41] and, to the best of our knowledge, their cytotoxicity has only been reported once [41]. On the other hand despite the interest for Pt(II) complexes, platinacycles with pyrazolyl ligands are scarce and studies on their biological activity have not been performed so far.…”

1,3-Diketones. Synthesis and properties

“…HBF 4 [47][48][49] (Scheme 41). Cross-coupling of the same β-diketones with N-substituted pyrrolidin-2-ones, catalyzed by Cu(OTf) 2 , afforded a large series of 2-substituted 1,3-dicarbonyl compounds 97 containing an oxopyrrolidine fragment [50] (Scheme 42).…”