(11R)-(–)-N,N′-Dimethylcinchonidinium diiodide

Abstract

Key indicatorsSingle-crystal X-ray study T = 296 K Mean '(C±C) = 0.007 A Ê R factor = 0.050 wR factor = 0.084 Data-to-parameter ratio = 21.5For details of how these key indicators were automatically derived from the article, see

Synthesis, Characterization, and DFT Investigation of IrIII Tolylterpyridine Complexes

“…All of the measurements were made with a Rigaku R-AxisRapid Imaging Plate diffractometer with graphite monochromated Mo-K α radiation (see Table 7). [25] Indexing was performed from three oscillations. The camera radius was 127.40 mm.…”

Trichlorido(dimethyl sulfoxide-κO)(di-2-pyridylamine-κ2N,N′)indium(III)

“…For related structures, see: Abedi et al (2011Abedi et al ( , 2012a; Ahmadi et al (2008); Clemente (2005); Dong et al (1987); Ilyuhin & Malyarik (1994); ; Kalateh, Norouzi et al (2008); Malecki et al (2011); Malyarick et al (1992); Shi & Jiang (2006); Shirvan & Haydari Dezfuli (2012); Yoshikawa et al (2004); Yousefi et al (2009).…”

“…(Malyarick et al, 1992), [In(phen)Cl 3 (DMSO)], (VI) (Dong et al, 1987), (Ahmadi et al, 2008), [In(5,5′-dmbipy)Cl 3 (MeOH)], (X) (Abedi et al, 2012b) (bipy = 2,2′-bipyridine, phen = 1,10-phenanthroline, DMSO = dimethyl sulfoxide, 4,4′-dmbipy = 4,4′-dimethyl-2,2′-bipyridine, 5,5′-dmbipy = 5,5′-dimethyl-2,2′-bipyridine, 4,4′-dtbipy = 4,4′-di-tert-butyl-2,2′-bipyridine, 4bt = 4,4′-bithiazole), have been synthesized and characterized by single-crystal X-ray diffraction methods. Di-2-pyridylamine (DPA) is a good bidentate ligand, and numerous complexes with DPA have been prepared, such as that of [Hg(DPA)Br 2 ], (XIV) (Kalateh, Norouzi et al, 2008), [Hg(DPA)Cl 2 ], (XV) (Yousefi et al, 2009), [Pt(DPA)Cl 4 ].DMF, (XVI) (Abedi et al, 2011), [Ir(DPA) 2 Cl 2 ](PF 6 ), (XVII) (Yoshikawa et al, 2004) (Malecki et al, 2011) and [Au(DPA)Cl 2 ]Cl, (XX) (Shi & Jiang, 2006). We report herein the synthesis and crystal structure of the title compound, (I).…”