“…Cyanoferrocene was prepared from ferrocenecarboxaldehyde via ferrocenecarboxaldoxime (Broadhead, Osgerby & Pauson, 1958). Crystals suitable for single-crystal diffraction were grown from cyclohexane solution.…”
“…Cyanoferrocene was prepared from ferrocenecarboxaldehyde via ferrocenecarboxaldoxime (Broadhead, Osgerby & Pauson, 1958). Crystals suitable for single-crystal diffraction were grown from cyclohexane solution.…”
“…Solvents were purified according to conventional procedures and were freshly distilled prior to use. Compounds 4 [14,15], 5 [16,17], 8 [13,18], ferrocenylnitrile [19], ferrocenylacetylene [20,21] and AIH 3 ' NMe3 [22] were prepared as described in the literature. IR spectra were recorded on a Bio-Rad Digilab FTS7 spectrometer.…”
Hydroalumination reaction was effectively carried out on ferrocenylnitrile in the synthesis of imidoalane cluster [HAl NCH 2 C 5 H 4FeCp]6 (3). Compound 3 exhibits a reversible electrochemical behavior. In the presence of ferrocenylmethanol, meta thesis reactions were carried out on [HAlNCH 2 (C 4 H)S)]6 (4) and [HAlNCH 2 Ph]6 (5) in the synthesis of [CpFeC s H4 CH 2 0AlNCH2CC 4 H)S)]6 (6) and [CpFeC s H 4 CH 2 0AlNCH 2 Ph]6 (7). The ferrocenylmethoxide groups present in these two com pounds show a single reversible oxidation wave, which suggests their electrochemical equivalence. Electrochemical studies were also carried out on the carbaalane [(AIHhCFcC CAlMAlNMe3hCCCH2Ph)6] (9), which exhibited a considerably broadened wave with shoulders preceding the main anodic and cathodic peak, and it can be assigned to weak electronic interactions between the individ ual ferrocenyl sites.
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