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Crystal Structure of Bis(<i>O</i>-Propyldithiocarbonato-<i>κ</i>²<i>S</i>,<i>S</i>′)(2,2′-bipyridine-<i>κ</i>²<i>N</i>,<i>N</i>′)nickel(II)

“…[1][2][3] Metal xanthate complexes and their reaction products with a variety of Lewis bases have been extensively studied. 4,5 To the best of our knowledge, the reaction products of nickel(II) propylxanthate with bidentate heterocyclic imines, such as 2,2¢-bipyridine, have not been very extensively studied, especially their crystallographic aspects.…”

Synthesis and Crystal Structure of Bis(<i>O</i>-ethyldithiocarbonato)bis(4-ethylpyridine)nickel(II)

“…1,2 The coordination chemistry of divalent transition metals with bidentate chelating dithiocarbonato ligands has been intensively investigated structurally. [3][4][5] This has been explained on the basis of their ability to interact strongly with Lewis bases, resulting in several physicochemical changes in dithiocarbonato ligands, which needs to be established structurally. As a part of our study on the characterization of adducts of bis(O-alkyldithiocarbonato)Ni(II) with nitrogen donor ligands, we report the synthesis and X-ray crystal structure of bis(Oethyldithiocarbonato)bis(4-ethylpyridine)nickel(II) in this paper.…”

Syntheses and Structures of Silver(I) and Palladium(II) Complexes with Ferrocenyl-phosphonodithiolate Ligands

“…The silver [18]. The average Ag -P bond lengths of 2.4745 (5) [17]. The two P -S bonds are nearly equal in length [P(1)-S(1) = 1.9843(7) and P(1)-S(2) = 1.9940(7)Å for 1, and P(1)-S(1) = 1.9742(7) and P(1)-S(2) = 1.9986 (6) [5].…”