“…Currently, nonlinear crystals suitable for producing high power mid and long-wave infrared laser mainly include MgO:PPLN [4], [5], CdSe [6]- [8], BaGa 4 Se 7 (BGSe) [9], [10], OP-GaAs [11], ZnGeP 2 (ZGP), and so on. Among various kinds of nonlinear optical materials, ZGP achieved the highest power of mid and long-wave infrared laser [12], [13], due to its high nonlinear coefficient (d 14 = 75 pm/V), high thermal conductivity, and acceptable damage threshold [14]. Limited by the transmittance range, ZGP needs to be pumped at a wavelength >2 μm.…”