1933
DOI: 10.1039/jr9330000674
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173. The free energy of the normal aliphatic alcohols in aqueous solution. Part I. The partial vapour pressures of aqueous solutions of methyl, n-propyl, and n-butyl alcohols. Part II. The solubilities of some normal aliphatic alcohols in water. Part III. The theory of binary solutions, and its application to aqueous-alcoholic solutions

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Cited by 174 publications
(54 citation statements)
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“…The The osmotic coefficient and activity coefficient values of glucose in aqueous medium increase as a function of concentration but the increase is found to be more pronounced in the case of binary aqueous β-CD solutions, as per earlier reported data [20], compared to glucose. It is observed that the increase in γ j 0 as a function of concentration is similar to aqueous solutions of monofunctional nonelectrolytes [39] and can be attributed to solute-solute association [40]. The water activity decreases slightly (or remain more or less constant within the limits of experimental accuracy) as a function of mole fraction of solute.…”
Section: Discussionmentioning
confidence: 95%
“…The The osmotic coefficient and activity coefficient values of glucose in aqueous medium increase as a function of concentration but the increase is found to be more pronounced in the case of binary aqueous β-CD solutions, as per earlier reported data [20], compared to glucose. It is observed that the increase in γ j 0 as a function of concentration is similar to aqueous solutions of monofunctional nonelectrolytes [39] and can be attributed to solute-solute association [40]. The water activity decreases slightly (or remain more or less constant within the limits of experimental accuracy) as a function of mole fraction of solute.…”
Section: Discussionmentioning
confidence: 95%
“…As reported in Table S3 (Supporting Information), the parameter sets W4C_1 and W3B_C give the best predictions for VLE of binary systems of water with methanol 45,46 and with ethanol, 49−51 respectively. The parameter sets W2B_1 and W4C_1 give best predictions for VLE of water with 1-propanol.…”
Section: Introductionmentioning
confidence: 96%
“…Butler et al [15,16] found that the logarithm of the infinite dilution activity coefficient of a compound in water is approximately an additive function of the groups present in that compound. Later, Pierotti et al [17] extended and refined the relation for the same estimation using group contribution.…”
Section: Introductionmentioning
confidence: 98%