2,3-Bis(2-tert-butylphenylimino)butane

Abstract

Key indicatorsSingle-crystal X-ray study T = 295 K Mean (C-C) = 0.002 Å R factor = 0.039 wR factor = 0.104 Data-to-parameter ratio = 10.8For details of how these key indicators were automatically derived from the article, see

2,3-Bis[2-(trifluoromethyl)phenylimino]butane

“…Relevant bond lengths in the central core of (I) compare well with the corresponding ones in the recently reported related compound 2,3-bis(2-tert-butylphenylimino)butane (Ferreira et al, 2006), (II): in particular, 1.423 (3)/1.418 (2) Å for C-N, 1.280 (3)/1.277 (2) Å for C N, and 1.513 (4)/ 1.495 (3)Å for C-C, for (I)/(II), respectively.…”

Synthesis and X-ray crystallographic characterization of substituted aryl imines

“…The molecular structure of 1 shows a torsion angle formed by N1-C1-C1A-N1A of 180.0° (Fig. 5) which is consistent with the trans geometry of other a-diimines derived from 2,3-butanedione (177.5-180.0°) [33][34][35][36][37][38][39][40][41][42][43][44][45]. The substituted phenyl groups of 2-6 show an orthogonal conformation with respect to the naphthalene moiety which has also been observed with similar a-diimines [11,[46][47][48] and an a-iminoketone [49] derived from acenaphthenequinone (Fig.…”

2,3-Bis(2-ethylphenylimino)butane

“…The observed deviations between the C8/N1/C9/C10 and C3/C4/C5/C6/C7/C8 planes [70,8(1)°] can be related to steric factors because the presence of the ethyl groups in the phenyl rings. This kind of deviation was also observed in the crystalline structure of the similar compound 2,3-bis(2-tertbutylphenylimino)butane, 69.6 (1)° (Ferreira et al, 2006).…”