The demand for life-time power supply in Internet of Things (IoT) nodes is a challenge issue. Piezoelectric energy harvesting (PEH) is expected to meet the demand by harvesting vibration energy and converting it into electricity for the IoT nodes. This article presents a novel PEH power improvement circuit with thermoelectric energy assistance. The proposed circuit can extract energy from thermoelectric generator (TEG) to assist the PEH. Simulation and experimental platforms are built for testing the power generation performance of the proposed circuit. With the thermoelectric assistance of 0.1 V and 0.2 V, the harvested power can reach 3.4 times and 4 times that of the standard energy harvesting (SEH) circuit when the piezoelectric transducer (PZT) original open circuit voltage Voc,org = 8 V, respectively. The harvested power can be increased by 13.3% and 33.3% with the thermoelectric assistance of 0.1 V and 0.2 V, respectively.