241. Researches on monolayers. Part VII. Reactions of casein with dyes and other aromatic solutes and their relation to adsorption by protein fibres

Cameron, Angus E.; Giles, C. H.; MacEwan, T. H.

doi:10.1039/jr9580001224

Cited by 8 publications

(5 citation statements)

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“…Various monolayers have been investigated with regard to oxidation and decomposition Giles, 1957;Felmeister and Schaubman, 1969;Pilpel and Hunter, 1970).…”

Section: Oxidation and Decomposition Of Lipid Films Under Uv Irradiatmentioning

confidence: 99%

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Self-Assembly Monolayer Structures of Lipids and Macromolecules at Interfaces

Birdi¹

2002

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PREFACEThe information that science can extract from molecules that are essential for the processes of life can lead to better understanding of those processes. In natural selection during evolution (both prebiotic and biotic), physicochemical forces have been featured. A specific class of molecules, the amphiphiles, in aqueous environments exhibit self-assembly properties at liquid and solid interfaces. Such properties when combined with other forces require a special analysis. Of the self-assembly properties of amphiphiles, one is the formation of monomolecular films at both liquid-air and solid-air interfaces. During the last few decades, much has been reported in the literature on the formation of insoluble self-assembly monolayer (SAM) films of lipids and macromolecules (synthetic polymers and biopolymers) on the surface of water or at oil-water interfaces.The phenomenon of monolayer self-assembly has attracted considerable attention as a means of controlling molecular structures at interfaces. Studies of monomolecular films have been found to provide much physicochemical information on a molecular scale, which is useful for understanding many industrial and biological phenomena. For instance, the information obtained from lipid monolayer studies has been useful in determining the forces that stabilize various SAM structures found in lipid bilayers, vesicles, biological cell membranes, virus-cell fusion, emulsions, foams and films, and other self-assemblies. Current texts generally devote a single chapter to the characteristics of spread monolayers on liquids, and a researcher may have to look up a few hundred references to determine the procedures needed to investigate or analyze a particular phenomenon. Furthermore, there is an urgent need at this time for a text that discusses the state of the art regarding the surface phenomena exhibited by lipids and biopolymers, as they are relevant to a wide variety of surface and interfacial processes. During the last decade, the study of SAMs on solid surfaces has been aided greatly by developments in scanning tunneling microscopy (STM) and atomic force microscopy (AFM).The purpose of this book is to bring the reader up to date with the most recent experimental and the theoretical developments in relation to SAMs at liquid and solid surfaces. It is my intention to lead the researcher through the vast literature in such a way that he or she will be able to pursue particular investigation with suitable guidance. Such investigations may be industrial (emulsions, foams, dispersions, enhanced oil recovery, nonlinear optics) or biological [lipid-phase transitions, vesicles (drug targeting); bilayers, membranes, ion transport through membranes, sensors] in nature. The treatment in different parts of the text is based on the fundamental concepts of classical thermodynamics of surfaces (interfaces), i.e., the Gibbs adsorption theory. A large amount of experimental data from the literature has been included and critically examined from a vii viii PREFACE theoretical viewpoint...

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“…Various monolayers have been investigated with regard to oxidation and decomposition Giles, 1957;Felmeister and Schaubman, 1969;Pilpel and Hunter, 1970).…”

Section: Oxidation and Decomposition Of Lipid Films Under Uv Irradiatmentioning

confidence: 99%

“…A correlation was found between the fading and the versus A isotherms of various surface-active dyes investigated (Giles, 1957). Interaction between phenothiazine derivatives and films of lecithin were induced by ultraviolet (UV) irradiation (Felmeister and Schaubman, 1969).…”

Section: Oxidation and Decomposition Of Lipid Films Under Uv Irradiatmentioning

confidence: 99%

Self-Assembly Monolayer Structures of Lipids and Macromolecules at Interfaces

Birdi¹

2002

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“…Giles and his co-workers, [194][195][196][197][198] from refractive index measurements, studies in monolayer formation, and surface viscometry, have shown that interaction between dyes and polymers does take place depending on the structure of the dye and the polymer. Giles and his co-workers, [194][195][196][197][198] from refractive index measurements, studies in monolayer formation, and surface viscometry, have shown that interaction between dyes and polymers does take place depending on the structure of the dye and the polymer.…”

Section: B Location Of Dye and State Of Orientationmentioning

confidence: 99%

Physical Chemistry of Dyeing: State of Dye in Dyebath and in Substrate

Daruwalla

1974

The Chemistry of Synthetic Dyes

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“…A linear configuration is not essential for dye substantivity. 316,377,379,380 Most of the available evidence indicates that this is an important requirement for dye substantivity. 316,377,379,380 Most of the available evidence indicates that this is an important requirement for dye substantivity.…”

Section: E Dye-fiber Bondingmentioning

confidence: 99%

“…Monolayer studies by Giles et αΖ. 395 · 397,402 Evidence for such mechanisms has been obtained from monolayer studies 380 ' 397,403 and refractive index measurements in binary mixtures of polymers or model compounds and dyes. The tendency for the partition coefficient between cellulose acetate and water to increase with increasing molecular weight can be regarded as some evidence for dispersion forces between dye and substrate.…”

Section: E Dye-fiber Bondingmentioning

confidence: 99%

Physical Chemistry of Dyeing: Kinetics, Equilibrium, Dye-Fiber Affinity, and Mechanisms

Iyer

1974

The Chemistry of Synthetic Dyes

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241. Researches on monolayers. Part VII. Reactions of casein with dyes and other aromatic solutes and their relation to adsorption by protein fibres

Cited by 8 publications

References 0 publications

Self-Assembly Monolayer Structures of Lipids and Macromolecules at Interfaces

Self-Assembly Monolayer Structures of Lipids and Macromolecules at Interfaces

Physical Chemistry of Dyeing: State of Dye in Dyebath and in Substrate

Physical Chemistry of Dyeing: Kinetics, Equilibrium, Dye-Fiber Affinity, and Mechanisms

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