“…The surface work function (WF) of graphene plays a critical role in electronics, [1][2][3] energy storage, 4,5 and catalysts. 6,7 To achieve the desired material performance, a lot of approaches have focused on modulating the WF of graphene, including applying an external electric field, 8,9 surface modification, [10][11][12][13][14] layer stacking, 15,16 structural tailoring, 17,18 and heteroatom doping. 4,[19][20][21] Among these methods, chemical doping can effectively improve the thermodynamic properties of graphene with atomic controllability, 22 endowing it with diverse material properties and promoting its applications in energy storage and conversion.…”