“…18 Consequently, the limited performance of cathode materials for ZIBs greatly impede the development of high-performance EES systems. Thus far, manganese-based materials, 19,20 vanadium-based materials, 21–23 Prussian blue and its analogues, 24–26 Chevrel phase compounds, 27,28 and organic compounds have been exploited as cathode materials for ZIBs. 29,30 Amongst them, manganese-based materials are considered the most attractive cathodes for ZIBs and have been widely and intensively investigated owing to their low cost, natural abundance, low toxicity, multivalent states, high operation voltage, and satisfactory capacity (Fig.…”