“…[ 4–8 ] They have manifested a series of advantages including naturally‐passivated surface, thickness/strain/torsion‐regulated bandgap, excellent in‐plane carrier mobility, Si‐complementary metal‐oxide–semiconductor processing compatibility, outstanding flexibility, etc. Thus far, hundreds of 2DLMs have been explored including elemental semiconductors and their derivatives, [ 9–13 ] nitrides, [ 14 ] phosphides, [ 15,16 ] transition metal dichalcogenides, [ 17–28 ] post transition metal chalcogenides, [ 29–35 ] transition metal halides, [ 36–38 ] solid solutions, [ 39 ] multi‐element compounds, [ 40–56 ] topological insulators, [ 57,58 ] alloys, [ 59 ] etc. Their bandgap values range from 0 up to 6 eV, theoretically enabling them to meet the diverse practical applications in various wavebands.…”