3-(4-Bromophenyl)-N,N-dimethyl-3-oxopropan-1-aminium chloride

Abstract

The title compound, C11H15BrNO+·Cl−, was obtained as a precursor within our current program for the synthesis of new β-amino­alcohols via a Mannich-type reaction. The protonated amino N atom is hydrogen bonded to the chloride anion. With exception of one methyl group, the cation is approximately planar (r.m.s. deviation for all non H-atoms = 0.069 Å).

N-[2-(4-Methylbenzoyl)ethyl]propan-2-aminium chloride

“…In the title compound (I), ( Fig. 1), bond lengths and bond angles are within the range of expected values for this type of compound (Allen et al, 1987;Abonia et al, 2011;Tuzina et al, 2006). The protonated N1 atom forms a hydrogen bond to Cl1 (Table 1).…”

“…For hydrogenbond motifs, see: Bernstein et al (1995); Etter (1990). For some related structures, see: Abonia et al (2011); Tuzina et al (2006).…”

N-(2-Benzoylethyl)propan-2-aminium chloride

“…The geometric parameters of the title salt (I) in Fig. 1 are within the range of expected values for this type of compound (Allen et al,1987;Abonia et al, 2011;Tuzina et al, 2006).…”

“…For hydrogenbond motifs, see: Bernstein et al (1995); Etter (1990). For some related structures, see: Abonia et al (2011); Tuzina et al (2006).…”