Due to the high power density, fast charging speed, and long cycling stability, supercapacitors have been developed rapidly in the area of electrical energy storage devices in the past decades. During the application of supercapacitors, it was found that the properties of the electrode material can greatly affect the supercapacitor performance. Recently, electrode materials based on polymer waste‐derived carbon materials (PWCM) have attracted much attention because of the low preparation cost, good electrode performance, and great benefits for environmental protection. This review aims to describe the recent research development and summarize the investigation state in the field of the PWCM electrodes prepared from polyethylene, polypropylene, polyethylene terephthalate, polystyrene, etc. The preparation method and the electrode performance of the PWCM electrodes are compared. The relationship among the preparation methods, material structure, and electrochemical performance of the PWCM electrodes was explored. Furthermore, the prospects for the application of the PWCMs were provided.