4.14 Vinyl Substitutions with Organopalladium Intermediates

Butler, Eoin; Doran, Robert; Wilson, Claire M.; Guiry, Patrick J.

doi:10.1016/b978-0-08-097742-3.00420-1

Comprehensive Organic Synthesis II 2014

DOI: 10.1016/b978-0-08-097742-3.00420-1

|View full text |Cite

4.14 Vinyl Substitutions with Organopalladium Intermediates

Eoin Butler

Robert Doran

Claire M. Wilson

et al.

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...

Citation Types

Supporting

Mentioning

Contrasting

Year Published

2017

Publication Types

Select...

Article1

Relationship

Self Cite0

Independent1

Authors

Journals

Cited by 1 publication

References 432 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

Pd-Catalyzed Autotandem Reactions with N-Tosylhydrazones. Synthesis of Condensed Carbo- and Heterocycles by Formation of a C–C Single Bond and a C═C Double Bond on the Same Carbon Atom

Paraja

Valdés

2017

Org. Lett.

View full text Add to dashboard Cite

A new Pd-catalyzed autotandem reaction is introduced that consists of the cross-coupling of a benzyl bromide with a N-tosylhydrazone followed by an intramolecular Heck reaction with an aryl bromide. During the process, a single and a double C-C bond are formed on the same carbon atom. Two different arrangements for the reactive functional groups are possible, rendering great flexibility to the transformation. The same strategy led to 9-methylene-9H-fluorenes, 9-methylene-9H-xanthenes, 9-methylene-9,10-dihydroacridines, and also dihydropyrroloisoquinoline and dihydroindoloisoquinoline derivatives.

show abstract

Pd-Catalyzed Autotandem Reactions with N-Tosylhydrazones. Synthesis of Condensed Carbo- and Heterocycles by Formation of a C–C Single Bond and a C═C Double Bond on the Same Carbon Atom

Paraja

Valdés

2017

Org. Lett.

View full text Add to dashboard Cite

show abstract

scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.

Contact Info

customersupport@researchsolutions.com

10624 S. Eastern Ave., Ste. A-614

Henderson, NV 89052, USA

This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.

Blog Terms and Conditions API Terms Privacy Policy Contact Cookie Preferences Do Not Sell or Share My Personal Information

Made with 💙 for researchers

Part of the Research Solutions Family.

4.14 Vinyl Substitutions with Organopalladium Intermediates

Cited by 1 publication

References 432 publications

Pd-Catalyzed Autotandem Reactions with N-Tosylhydrazones. Synthesis of Condensed Carbo- and Heterocycles by Formation of a C–C Single Bond and a C═C Double Bond on the Same Carbon Atom

Pd-Catalyzed Autotandem Reactions with N-Tosylhydrazones. Synthesis of Condensed Carbo- and Heterocycles by Formation of a C–C Single Bond and a C═C Double Bond on the Same Carbon Atom

Contact Info

Product

Resources

About