1990
DOI: 10.1002/ange.19901020629
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4,7‐Dimethyl‐4,7‐dihydro[1,2,5]thiadiazolo[3,4‐b]‐pyrazin, ein neuer Elektronendonor mit einem 12π‐Elektronensystem

Abstract: Ein sehr niedriges erstes Oxidationspotential (0.15 V vs. SCE) charakterisiert die 12π‐Elektronen‐Titelverbindung 1, die durch Reduktion des entsprechenden 14π‐Elektronensystems mit Kalium und Abfangen des Dianions mit Methyliodid entsteht. Mit dem Elektronenacceptor 2 bildet 1 leitfähige Charge‐Transfer‐Komplexe (σ = 5.6 x 10−2 S cm−1).

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Cited by 3 publications
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“…Benzidine‐type electron donors fused with bis‐2,1,3‐chalcogenediazole units (Scheme ) were synthesized 66b. Electrostatic interactions between heterocycles may be a useful tool, which is suggested by various types of molecular networks formed by the chalcogen–nitrogen contacts in the crystals of 2,1,3‐chalcogenadiazole derivatives 66c,66d. Derivatives 62a , b and 64a , b displayed multistage redox behavior.…”
Section: Synthesis Chemical Properties Sulfur Extrusion and Mismentioning
confidence: 99%
“…Benzidine‐type electron donors fused with bis‐2,1,3‐chalcogenediazole units (Scheme ) were synthesized 66b. Electrostatic interactions between heterocycles may be a useful tool, which is suggested by various types of molecular networks formed by the chalcogen–nitrogen contacts in the crystals of 2,1,3‐chalcogenadiazole derivatives 66c,66d. Derivatives 62a , b and 64a , b displayed multistage redox behavior.…”
Section: Synthesis Chemical Properties Sulfur Extrusion and Mismentioning
confidence: 99%