Russian Journal of Organic Chemistry

2003

DOI: 10.1023/a:1025540203292

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V. S. Zavgorodnii¹,

S. A. Klyuchinskii²,

Jean‐François Fauvarque³

et al.

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Cited by 3 publications

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Formation of Alkanes and Arenes by Coupling Reactions

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2018

Comprehensive Organic Transformations

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Symmetrical or Intramolecular Coupling Unsymmetrical Coupling

Formation of Alkanes and Arenes by Coupling Reactions

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,

²

2018

Comprehensive Organic Transformations

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Symmetrical or Intramolecular Coupling Unsymmetrical Coupling

Reaction of 4‐(N,N‐Dimethylaminophenyl)magnesium Bromide with Palladium Tetrakis(triphenylphosphine).

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et al. 2003

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Reaction of 4-(N,N-Dimethylaminophenyl)magnesium Bromide with PalladiumTetrakis(triphenylphosphine). -The palladium-catalyzed cross coupling reaction of bromobenzonitrile (I) with dimethylaminophenylmagnesium bromide (II) is studied in detail concerning the influence of reaction conditions on the ratio of cross coupling (IV) to C≡N addition product (III). Various reaction conditions are studied, including temperature, catalyst concentration, order of reagent addition, precomplexation and overall reaction times, and the optimal reaction conditions for the formation of adduct (III) or cross coupling product (IV) are presented. -(ZAVGORODNII, V. S.; KLYUCHINSKII, S. A.; FAUVARQUE, J.-F.; LALLEVE, G.; BISPO, I.; Russ. J. Org. Chem. 39 (2003) 2, 219-225; St. Petersburg State Technol. Inst., St. Petersburg 198013, Russia; Eng.) -Mischke 46-057

Suzuki–Miyaura coupling reaction of aryl chlorides using di(2,6-dimethylmorpholino)phenylphosphine as ligand

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et al. 2007

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