8-Hydroxy-2-methylquinolinium tetrachlorido(quinolin-8-olato-κ²N,O)stannate(IV) acetonitrile monosolvate

Abstract

In the title solvated salt, (C10H10NO)[SnCl4(C9H6NO)]·CH3CN, the SnIV atom is chelated by the N,O-bidentate 8-hydroxy­quinolinate ligand and four chloride ions, generating a distorted SnONCl4 octa­hedral coordination geometry for the metal. In the crystal, the cations are linked to the anions and the solvent mol­ecules by O—H⋯O and N—H⋯N hydrogen bonds, respectively.

Formation of R44(8)$R_4^4(8)$ ring in chloride salts of 8-hydroxyquinolinium derivatives: synthesis, structural, and theoretical studies

“…Upon protonation of the pyridine ring in the quinolinium salts of these compounds, new intramolecular N-H···O hydrogen bonds form, and the hydroxyl oxygen establishes intermolecular hydrogen bonds with counter ions or solvent molecules [35,37]. In the neutral or deprotonated forms, 8-hydroxyquinolines could act as chelating ligands [38][39][40][41]. In these structures, the pyridine nitrogen and phenolic oxygen act as electron donor atoms forming a 5-membered chelate ring.…”

10-Hydroxybenzo[h]quinolinium tetrachlorido(2-methylquinolin-8-olato-κ2N,O)stannate(IV) methanol disolvate

“…Crystal data (C 13 H 10 NO)[SnCl 4 (C 10 H 8 NO)]Á-2CH 4 O M r = 678.97 Triclinic, P1 a = 7.5645 (2) Å b = 10.1112 (3) Å c = 17.7837 (5) Å = 98.105 3= 95.653 (3) = 97.509 (3) V = 1325.56 (6) Å 3 Z = 2 Mo K radiation = 1.40 mm À1 T = 100 K 0.30 Â 0.30 Â 0.10 mm Data collection: CrysAlis PRO (Agilent, 2010); cell refinement: CrysAlis PRO; data reduction: CrysAlis PRO; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008); molecular graphics: X-SEED (Barbour, 2001); software used to prepare material for publication: publCIF (Westrip, 2010). We have been attempting to synthesize mixed-chelate tin(IV) compounds; in a recent study, we reacted stannic chloride with 8-hydroxyquinoline and 2-methyl-8-hydroxyquinoline (Vafaee et al, 2010). However, the reaction yielded 2methyl-8-hydroxyquinolinium tetrachlorido(quinolin-8-olato)stannate as an acetonitrile solvate.…”

“…For the related compound, solvated 2-methyl-8-hydroxyquinolinium tetrachlorido(quinolin-8-olato)stannate(IV), see: Vafaee et al (2010).…”