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Ishizu, Koji; Satoh, Junichiro; Tsubaki, Keiichiro

doi:10.1023/a:1017961707300

Cited by 21 publications

(18 citation statements)

References 10 publications

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“…This suggests that these polymer brushes are molecularly dissolved in the dilute solution. Similar tendencies were also observed in double-cylinder-type [10][11][12][13] and prototype [21,22] copolymer brushes. The translational diffusion coefficient D 0 can Fig.…”

Section: Solution Properties Of Peg Brushes and Ab-type Brush-block-bsupporting

confidence: 78%

“…1b) by alternating free-radical copolymerizations of binary macromonomers [19,20]. They have also investigated their dilute-solution properties and aggregation behaviors in aqueous media [12,13,21,22]. As a result, such copolymer brushes were molecularly dissolved in a dilute solution and took geometrically anisotropic conformation such as cylinder increasing aspect ratio.…”

Section: Introductionmentioning

confidence: 99%

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Architecture and solution properties of AB-type brush–block–brush amphiphilic copolymers via ATRP techniques

Ishizu

Satoh

Sogabe

2004

Journal of Colloid and Interface Science

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Section: Solution Properties Of Peg Brushes and Ab-type Brush-block-bsupporting

confidence: 78%

Section: Introductionmentioning

confidence: 99%

Architecture and solution properties of AB-type brush–block–brush amphiphilic copolymers via ATRP techniques

Ishizu

Satoh

Sogabe

2004

Journal of Colloid and Interface Science

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“…To explore the phase-separated cylinder brush structures, we constructed large aggregates of copolymer brushes [21,27] (see Fig. 10).…”

Section: Prototype Copolymer Brushesmentioning

confidence: 99%

Architecture of multi-component copolymer brushes

Ishizu¹,

Tsubaki²,

Satoh³

et al. 2002

Designed Monomers and Polymers

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Abstract-In the rst part of this article, the method for the preparation of diblock copolymer brushes from free radical homopolymerization of the corresponding diblock macromonomers is reviewed. These diblock copolymer brushes formed a unimolecular structure in dilute solution. Moreover, it was speculated from angular dependence measurements that diblock copolymer brushes with high aspect ratios took a geometrical anisotropic conformation, such as a cylinder. The cylinder brushes were also derived by cross-linking internal domains of the diblock copolymer brush. The second part reviews the synthesis of prototype amphiphilic copolymer brushes by alternating free radical copolymerization of binary macromonomers. To determine the phase-separated cylindrical domains of alternating copolymer brushes, large aggregates of copolymer brushes in water were constructed. The alternating copolymer brushes led to self-assembliesamong hydrophobic domains during micelle formation.

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“…However, for randomly distributed different SCs along the backbone, these MBs are commonly known as mixed or statistical MBs (Scheme , 2C). Compared to other MBs, the incorporation of two different types of SCs provides MBs with extra structural versatility and unique aggregation properties . When the two SCs have different natures (i.e.…”

Section: Structures and Compositions Of Mbs Synthesized Via Atrpmentioning

confidence: 99%

Atom transfer radical polymerization as a powerful tool in the synthesis of molecular brushes

Hadasha

Klumperman

2014

Polymer International

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Macromolecules with complex architectures such as molecular brushes (MBs) have received much attention over the last two decades. This interest is largely due to their potential applications in many fields, such as drug delivery and electronics, among others. The synthesis of such complex macromolecules can only be achieved via the use of controlled polymerization techniques such as atom transfer radical polymerization (ATRP). This review highlights the use of ATRP in the synthesis of MBs.

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Cited by 21 publications

References 10 publications

Architecture and solution properties of AB-type brush–block–brush amphiphilic copolymers via ATRP techniques

Architecture and solution properties of AB-type brush–block–brush amphiphilic copolymers via ATRP techniques

Architecture of multi-component copolymer brushes

Atom transfer radical polymerization as a powerful tool in the synthesis of molecular brushes

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