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Bazhenov, Yu. P.; Kas’yanova, L. Z.; Bokin, A. I.; Кутепов, Б. И.; Хазипова, А. Н.; Travkin, E. A.; Shchadneva, N. А.; Хуснутдинов, Р. И.; Джемилев, У. М.

doi:10.1023/a:1024694327338

Cited by 12 publications

(10 citation statements)

References 3 publications

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“…Although aiming for cis -pinane, Bazhenov et al obtained 80 wt % ρ-cymene over dealuminated zeolite Y, an outstanding result in a liquid-phase operation . A slightly lower yield (70 wt %) was also obtained by Jaramillo et al with a H 3 PW 12 O 40 · x H 2 O/SiO 2 catalyst (liquid phase) .…”

Section: α-Pinene Upgrading Techniquesmentioning

confidence: 97%

Catalytic Upgrading of Extractives to Chemicals: Monoterpenes to “EXICALS”

2015

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Section: α-Pinene Upgrading Techniquesmentioning

confidence: 97%

Catalytic Upgrading of Extractives to Chemicals: Monoterpenes to “EXICALS”

2015

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“…Typically, a-pinene is not employed in polymerizations, as it is signicantly less reactive than b-pinene; however, it can be hydrogenated, pyrolyzed, oxidized, and isomerized into b-pinene or mixtures of other terpenes and terpenoids, such as a-phellandrene, myrcene, and menthol. [120][121][122][123] b-Pinene, a-phellandrene, myrcene, and menthol are among pinene derivatives that have been studied in controlled polymerizations. [117][118][119][120] Myrcene-and menthol-based polymers and their potential as rubbery blocks are discussed throughout Section 3.2 whereas poly(b-pinene), poly(a-phellandrene), and their BPs are reviewed in this section.…”

Section: Blocks Derived From Pine Resinmentioning

confidence: 99%

Biobased building blocks for the rational design of renewable block polymers

et al. 2014

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Block polymers (BPs) derived from biomass (biobased) are necessary components of a sustainable future that relies minimally on petroleum-based plastics for applications ranging from thermoplastic elastomers and pressure-sensitive adhesives to blend compatibilizers. To facilitate their adoption, renewable BPs must be affordable, durable, processable, versatile, and reasonably benign. Their desirability further depends on the relative sustainability of the renewable resources and the methods employed in the monomer and polymer syntheses. Various strategies allow these BPs' characteristics to be tuned and enhanced for commercial applications, and many of these techniques also can be applied to manipulate the wide-ranging mechanical and thermal properties of biobased and self-assembling block polymers. From feedstock to application, this review article highlights promising renewable BPs, plus their material and assembly properties, in support of de novo design strategies that could revolutionize material sustainability.

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“…After solvent evaporation, was obtained 682 mg (yielding 99%) of colorless oil which was characterized as (-)-pinane by NMR/EIMS analysis and comparison with literature data. 24 (-)-Pinane.…”

Section: Hydrogenation Of (-)-A-pinenementioning

confidence: 99%

In vitro trypanocidal evaluation of pinane derivatives from essential oils of ripe fruits from Schinus terebinthifolius Raddi (Anacardiaceae)

et al. 2012

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Essential oils of ripe fruits from Schinus terebinthifolius (Anacardiaceae), obtained using a pilot extractor and a Clevenger apparatus were chemically characterized. Due the high amount of (-)- α-pinene in both oils, this monoterpene was tested against the protozoan parasite Trypanosoma cruzi, showing a moderate potential (IC50 63.56 µg/mL) when compared to benznidazole (IC50 43.14 µg/mL). Otherwise, (-)- α-pinene oxide did not showed anti-trypanosomal activity (IC50 > 400 µg/mL) while (-)-pinane showed an IC50 of 56.50 µg/mL. The obtained results indicated that the epoxydation of α-pinene results to the loss of the anti-parasitic activity while its hydrogenation product, contributed slightly to the increased activity

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Cited by 12 publications

References 3 publications

Catalytic Upgrading of Extractives to Chemicals: Monoterpenes to “EXICALS”

Catalytic Upgrading of Extractives to Chemicals: Monoterpenes to “EXICALS”

Biobased building blocks for the rational design of renewable block polymers

In vitro trypanocidal evaluation of pinane derivatives from essential oils of ripe fruits from Schinus terebinthifolius Raddi (Anacardiaceae)

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