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Cited by 16 publications
(8 citation statements)
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“…Among relevant studies we can distinguish the works aimed at synthesizing the binuclear Сu 2+ complexes, where the β diketonate fragments in a molecule are linked through the m xylylene and 2,7 naphthalenediyl bis methylene spacers, and at studying their metal receptor properties. 11- 13 The binuclear V 2+ and V 3+ complexes were also synthesized from the ligand with the m xylylene spacer, and they are promising catalysts of redox pro cesses. 14 The use of ligands with two spatially separated β di ketonate groups made it possible to create the coordina tion "host" polymers with architecture of "molecular shelves" of high strength and capacity.…”
mentioning
confidence: 99%
“…Among relevant studies we can distinguish the works aimed at synthesizing the binuclear Сu 2+ complexes, where the β diketonate fragments in a molecule are linked through the m xylylene and 2,7 naphthalenediyl bis methylene spacers, and at studying their metal receptor properties. 11- 13 The binuclear V 2+ and V 3+ complexes were also synthesized from the ligand with the m xylylene spacer, and they are promising catalysts of redox pro cesses. 14 The use of ligands with two spatially separated β di ketonate groups made it possible to create the coordina tion "host" polymers with architecture of "molecular shelves" of high strength and capacity.…”
mentioning
confidence: 99%
“…Cu 2 (NBA) 2 {NBAH 2 is 3,3 0 -[naphthalene-2,7-diylbis(methylene)]bis(pentane-2,4-dione)} forms a crystalline solvate with two CHCl 3 molecules, in which the CuÁ Á ÁCu distance is 7.349 (1) Å at room temperature (Maverick et al, 1986) and 7.298 (1) Å at 100 K (Burton et al, 2002). 4diazabicyclo[2.2.2]octane), the CuÁ Á ÁCu distance is 7.403 (4) Å (Maverick et al, 1986), with -2,5-dimethylpyrazine it is 7.559 (2) and 7.596 (2) Å (Maverick et al, 1990), and with -2methylpyrazine it is 7.4801 (8) Å (Maverick et al, 2001). For related literature, see: Martin et al (1959).…”
Section: Related Literaturementioning
confidence: 99%
“…Accordingly, the acetonitriles in [Cu 2 (m-xba) 2 (CH 3 CN) 2 ] are exo-coordinated with the CuÁ Á ÁCu distance being 4.830(1) A ˚. 7 On increasing the spacer length by introducing a napthalylene bridge, the dicopper(II) complex [Cu 2 (nba) 2 ] could accommodate two chloroform molecules inside the void space (CuÁ Á ÁCu = 7.349(1) A ˚)8 and also could intramolecularly coordinate bidentate Lewis bases such as pyrazine derivatives (CuÁ Á ÁCu = 7.480(1) A ˚)7 and diazabicyclooctane (CuÁ Á ÁCu = 7.403(4) A ˚). 8 Further increase of the void space inside the metallacycle was accomplished by using m-terphenyl as the spacer.…”
Section: Introductionmentioning
confidence: 99%