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Rauth, Goutam Kumar; Pal, Sanjib; Sinha, Chittaranjan

doi:10.1023/a:1012035714276

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2003

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“…We have designed two new classes of arylazoheterocycles: 1-alkyl-2-(arylazo)imidazoles [30][31][32][33][34][35][36][37][38][39][40] and 2-(arylazo)pyrimidines. [41][42][43][44] Emphasis is laid on 2-(arylazo)imidazoles because of biological importance of imidazole 49,50 and synthetic simplicity over other azoheterocycles.…”

Section: Introductionmentioning

confidence: 99%

Synthesis, spectral characterization and redox properties of iron (II) complexes of 1-alkyl-2-(arylazo)imidazole

2003

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Iron (II) complexes of 1-alkyl-2-(arylazo)imidazoles (p-R-C 6 H 4-N=N-C 3 H 2 NN-1-R′, R = H (a), Me (b), Cl (c) and R′ = Me (1/3), Et (2/4) have been synthesized and formulated as tris-chelates .) R Fe(Raai 2 3 + ′ They are characterized by microanalytical, conductance, UV-Vis, IR, magnetic (polycrystalline state) data. The complexes are low spin in character, 6 2 g t (Fe(II)) configurations.

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