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Jackson, S. David; Anderson, David S.; Kelly, Gordon; Lear, Timothy; Lennon, David; Watson, Simon R.

doi:10.1023/a:1023640100556

Cited by 17 publications

(1 citation statement)

References 11 publications

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“…Methanol solvent has been previously reported to act as a reducing or oxidizing agent due to its thermal breakdown mechanism forming carbon dioxide and hydrogen, an explanation for this variation from ethanol deposits despite the similar solvent properties. 228 Carmalt et al used hexane or DCM in an in situ AACVD reaction for NbS 2 and TaS 2 films, which showed significantly different sized cluster morphologies depending on the solvent, however, the larger, and less uniform, clusters were grown using hexane for TaS 2 but DCM for NbS 2 . 229…”

Section: Precursor Design and Growth Criteria For Semiconductor Mater...mentioning

confidence: 99%

A chemist's guide to photoelectrode development for water splitting – the importance of molecular precursor design

Harris-Lee,

Marken,

Bentley

et al. 2023

EES. Catal.

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Section: Precursor Design and Growth Criteria For Semiconductor Mater...mentioning

confidence: 99%

A chemist's guide to photoelectrode development for water splitting – the importance of molecular precursor design

Harris-Lee,

Marken,

Bentley

et al. 2023

EES. Catal.

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Reaction between methanol and acetic acid catalyzed by SiO₂‐supported V‐P‐O catalyst in oxygen atmosphere

Shen

Wang

et al. 2019

Can J Chem Eng

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SiO 2 -supported V-P-O catalysts prepared by the incipient-wetness impregnation method beginning with ammonium metavanadate and phosphoric acid were used in the catalytic reaction between methanol and acetic acid in an oxygen atmosphere. The SiO 2 -supported V-P-O catalysts were composed of VOPO 4 and (VO) 2 P 2 O 7 phases. Both the acidic and alkaline sites were co-present in the catalysts. The vanadium species catalyzed the oxidation of methanol to formaldehyde. The V-P-O(20-30 wt%)/SiO 2 catalysts with a P/V mole ratio of 2:1 exhibited higher catalytic activity for the formation of acrylic acid and methyl acrylate with a total selectivity of ∼28 % at 380°C. The acid sites of the catalysts also catalyzed the formation of methyl acetate with a selectivity of ∼65 %. Methanol can be an alternative to formaldehyde for the synthesis of both acrylic acid and methyl acrylate through the aldol condensation reaction.

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The Effect of Solvent on the Phase of Titanium Dioxide Deposited by Aerosol‐assisted CVD

Edusi

Sankar

Parkin

2012

Chemical Vapor Deposition

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Titanium (IV) isopropoxide (TTIP) in methanol, ethanol, hexane, dichloromethane, and isopropanol solvents is used to deposit titanium dioxide thin films on glass and steel substrates at 550 8C using aerosol-assisted (AA)CVD. X-ray diffraction (XRD), and Raman spectra of the as-deposited films show that using methanol as the carrier solvent produces exclusively rutile films on steel, and predominantly rutile on glass substrates, while the use of the other solvents produces exclusively anatase phase on the steel under the same conditions. TiO 2 is also deposited by AACVD from a mixture of ethanol and methanol solvents. As little as 15% of methanol in ethanol produces rutile as the predominant phase. Using a dye-ink test, the titanium dioxide thin films produced with ethanol are shown to be more active photocatalysts than films produced with methanol. All the films show photoinduced superhydrophilicity but, surprisingly, films stored in the dark have a water contact angle above 1008.

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Untitled

Cited by 17 publications

References 11 publications

A chemist's guide to photoelectrode development for water splitting – the importance of molecular precursor design

A chemist's guide to photoelectrode development for water splitting – the importance of molecular precursor design

Reaction between methanol and acetic acid catalyzed by SiO₂‐supported V‐P‐O catalyst in oxygen atmosphere

The Effect of Solvent on the Phase of Titanium Dioxide Deposited by Aerosol‐assisted CVD

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Untitled

Cited by 17 publications

References 11 publications

A chemist's guide to photoelectrode development for water splitting – the importance of molecular precursor design

A chemist's guide to photoelectrode development for water splitting – the importance of molecular precursor design

Reaction between methanol and acetic acid catalyzed by SiO2‐supported V‐P‐O catalyst in oxygen atmosphere

The Effect of Solvent on the Phase of Titanium Dioxide Deposited by Aerosol‐assisted CVD

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Reaction between methanol and acetic acid catalyzed by SiO₂‐supported V‐P‐O catalyst in oxygen atmosphere