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Abstract

Crystal Structures of Hydrazinium(II) Salts of [SbF 6] and [Sb2F11] -. -Compounds (III) (yield given in g) and (IV) are synthesized in anhydrous HF and their crystal structures are determined by single crystal XRD. (III) crystallizes in the triclinic space group P1 with Z = 2. The structure is composed of [N2H6] 2+ cations and [Sb 2F11] groups. In disagreement with previous reports based on powder XRD, (IV) crystallizes in the monoclinic space group C2/c with Z = 8. The structure consists of [N 2H6] 2+ cations and [SbF6]anions held together by hydrogen bonds. -(MAZEJ*

Complexation between N-allylmorpholinium derivatives and copper(I) halides. Synthesis and crystal structure of π-complex {[C4H8ONH(C3H5)]+}2[Cu2Cl4]2−

“…The {[ C 4 H 8 ONH ( C 3 H 5 )] + } 2 [Cu 2 Cl 4 ] 2units are united into a three-dimensional framework through C−H···Cl contacts (Table 4), which, according to the criteria in [14][15][16], can be regarded as moderately strong hydrogen bonds, and through short N−H···Cl contacts (H···Cl 2.0(1)-2.2(1) Å) involv- Cu(1) 0.57804(7) 0.1103(2) 0 3.23(4) Cu (2) 0.67576 (7) (1) 138 (6) ing the protonated N atoms of the cations. Note that the terminal Cl(1) and Cl(2) atoms in the Cu(1) coordination sphere form two strong hydrogen bonds, while the terminal Cl(4) atom in the Cu(2) environment form no C-H···Cl contacts.…”

“…In structurally studied copper(I) π -complexes, the cationic forms of N-allyl derivatives are used for coordination by a metal particularly through the C=C bonds [1][2][3][4]. The absence of N atoms from the coordination sphere of copper enhances the efficiency of the Cu(I)-C=C π -interaction [5].…”

Synthesis and Crystal Structure of the Heterovalent Copper(I,II) π-Complex Cu7Br6.48Cl1.52 ⋅ 2C3N3(OC3H5)3

“…Both the influence of the Cl/Br substitution on the efficiency of the Cu-(C=C) π -interaction and the inverse influence of the C=C bond in the coordination sphere of the metal on the degree of chloride-bromide substitution have been estimated previously in the studied heteroligand copper(II) π -complexes with allyl het- [4,5]. The copper(I) chloride and bromide π -complexes with 2,4,6-triallyloxy-1,3,5-triazine are convenient objects for the study of the chloride-bromide substitution, since they are isostructural and contain four crystallographically independent metal atoms with different coordination environments.…”

Olefin-Copper(I) Complexes and their Properties

“…to afford a number of olefin-copper(I) complexes. [11][12][13] Goreshnik group used CuBr 2 or CuCl 2 Á2H 2 O of and 1-allyl-4-aminopyridium bromide in ethanol solution to afford olefin-copper(I) complexes under alternating-current electrochemical synthesis (equation (5)). …”

“…The rational design and construction of hybrid organicinorganic zeolite analogues for enantioseparation and catalysis are of intense current interest [79,80]. The inclusion of enantiomerically pure chiral compounds (12) (13) (14) (15) (16) (17) into microporous materials (zeotypes) for enantiomer separation, as well as chiral synthesis and catalysis, has been a continuing challenge and represents an ambitious goal for chemists [81,82]. Currently known materials capable of offering enantiomeric separation and catalysis tend to be 2-D layer-type structures that are able to intercalate guests [83,84].…”