1998
DOI: 10.1023/a:1008838813120
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Abstract: Ultrafine-grained, nanophase coatings of hydroxyapatite were synthesized by electrocrystallization from dilute electrolytes ([Ca]=6.1 x 10-4 M, [phosphate]=3.6 x 10-4 M) at pH values comparable with the biological pH. At these comparatively low supersaturations, hydroxyapatite is shown to be precipitated without the formation of a precursor phase. A description of the sequence of events occurring at the electrode-electrolyte interface is given to explain the mechanism involved in the direct formation of nanoph… Show more

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Cited by 162 publications
(37 citation statements)
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“…For such applications, thin films of hydroxyapatite (HAP) were prepared using an ED technique (electrophoretic deposition (EPD) [21,22] or electrolytic deposition (ELD) [23]. HAP is an established implant material because its chemical composition is similar to that of bone tissue.…”
Section: Specific Advantages Of Electrochemical Depositionmentioning
confidence: 99%
“…For such applications, thin films of hydroxyapatite (HAP) were prepared using an ED technique (electrophoretic deposition (EPD) [21,22] or electrolytic deposition (ELD) [23]. HAP is an established implant material because its chemical composition is similar to that of bone tissue.…”
Section: Specific Advantages Of Electrochemical Depositionmentioning
confidence: 99%
“…During cathodic polarization, the pH value near the electrode increases owing to hydrogen evolution. This can be used to deposit CPP on titanium surfaces from supersaturated solutions because their solubility decreases with rising pH value (Shirkhanzadeh 1998;Rößler et al 2003;Cheng et al 2004). The structure of the deposited CPP encompasses amorphous CPP, brushit, octacalcium phosphate and HAP, depending on electrolyte composition, temperature and electrochemical parameters.…”
Section: Electrochemical Methodsmentioning
confidence: 99%
“…13 The cations, such as Ca 2+ , have the ability to rapidly deposit around the cathode, and anions, such as PO 4 3− , HPO 4 2− and OH − , subsequently aggregate around the cations. 14 These depositions result in the formation of hydroxyapatite at the cathode, which promotes bone formation. 14 Attempts to induce osteogenesis with electric forces have used various methods, including direct electrical current, 7 capacitive coupling, 15 and inductive coupling.…”
Section: Introductionmentioning
confidence: 99%
“…14 These depositions result in the formation of hydroxyapatite at the cathode, which promotes bone formation. 14 Attempts to induce osteogenesis with electric forces have used various methods, including direct electrical current, 7 capacitive coupling, 15 and inductive coupling. 9 However, the requirement of external devices to generate an electrical potential, invasive procedural methods, and high infection rates have considerably halted the application of electric stimulation in clinical settings.…”
Section: Introductionmentioning
confidence: 99%