Abstract:An Al0.20Ga0.80As solar cell with a band gap graded from 1.64 eV at the junction to 1.72 eV at the surface has been fabricated using metalorganic chemical vapor deposition. An efficiency of 19.2% has been measured under 1-sun, AM2 simulated conditions with an open circuit voltage of 1.18 V, a short circuit density of 14.5 mA/cm2, and a fill factor of 0.83.
“…The design is technologically feasible, as it has been shown that graded In x Ga 1 À x N layers can be grown over the entire composition range using the Energetic Neutral Atom Beam Lithography and Epitaxy (ENABLE) process [20]. Compositional grading in solar cells has previously been considered in the Al x Ga 1 À x As materials system, where it was found to reduce surface recombination losses [21,22]. Grading has also been used in CuIn x Ga 1 À x Se 2 cells to increase the efficiencies in thin devices [23].…”
“…The design is technologically feasible, as it has been shown that graded In x Ga 1 À x N layers can be grown over the entire composition range using the Energetic Neutral Atom Beam Lithography and Epitaxy (ENABLE) process [20]. Compositional grading in solar cells has previously been considered in the Al x Ga 1 À x As materials system, where it was found to reduce surface recombination losses [21,22]. Grading has also been used in CuIn x Ga 1 À x Se 2 cells to increase the efficiencies in thin devices [23].…”
“…These are listed in Table . We also calculated the EREs of III–V/Si and III–V solar cells in using this approach. The results are listed in Table .…”
Section: External Radiative Efficiencies Of State‐of‐the Art Iii/v Onmentioning
The paper presents a quantitative approach to the investigation and comparison of the material qualities of III-V on silicon (III-V/Si) solar cells by using external radiative efficiencies. We use this analysis to predict the limiting efficiencies and evaluate the criteria of material quality in order to achieve high efficiency III-V/Si solar cells. This result yields several implications for the design of high efficiency III-V/Si solar cells.
“…These are listed in Table I. We also calculated the EREs of III-V/Si and III-V solar cells in [15][16][17] using this approach. The results are listed in Table II.…”
Section: External Radiative Efficiencies Of State-of-the Art Iii/v Onmentioning
confidence: 99%
“…With these ERE values of each subcell, the limiting efficiency of this 2J cell is 36.5%. Because achieving the quality of state-of-the-art GaAs is still challenging for the candidate 1.73-eV III-V materials, a more realistic estimate is considering a top cell that matches the EREs of the AlGaAs reported in [15] or [16], which are both around 10 -4 . The limiting efficiency of this 2J cell is then 33.9%.…”
Section: Design Considerations Of Iii-v/si Solar Cellsmentioning
The paper presents a quantitative approach to the investigation and comparison of the material qualities of III-V on silicon (III-V/Si) solar cells by using external radiative efficiencies. We use this analysis to predict the limiting efficiencies and evaluate the criteria of material quality in order to achieve high-efficiency III-V/Si solar cells. This result yields several implications for the design of high-efficiency III-V/Si solar cells.
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