Time-domain measurements of the output waveforms of two 8-GHz high-efficiency power amplifiers, a 1-GHz frequency doubler, and a 5-GHz frequency doubler are presented in this paper. A new photoconductive probe has enabled nonintrusive time-domain voltage measurements, which confirm switched-mode class-E and class-F amplifier operation. In order to analyze nonlinear amplifiers designed to deliver a sinusoidal wave to the load, voltages at characteristic points inside the circuit need to be known. In multipliers, waveform measurements track harmonic leakage, expediting the design cycle. The highimpedance probe used here is an optoelectronic sampler, which can sense the charge on an exposed interconnect or the field associated with a buried interconnect. These electric-field data are then converted into voltage.