Reduction–oxidation
(redox) reaction conditions, which are of great importance for the
soil
chemistry of coastal marshes, can be temporally dynamic. We present
a transect of cores from northwest Florida wherein radical postdepositional
changes in the redox regime has created atypical geochemical profiles
at the bottom of the sedimentary column. The stratigraphy is consistent
along the transect, consisting of, from the bottom upward, carbonate
bedrock, a gray clay, an organic mud section, a dense clay layer,
and an upper organic mud unit representing the current saltwater marsh.
However, the geochemical signature of the lower organic mud unit suggests
pervasive redox reactions, although the interval has been identified
as representing a freshwater marsh, an unlikely environment for such
conditions. Analyses indicate that this discrepancy results from postdepositional
diagenesis driven by millennial-scale environmental parameters. Rising
sea level that led to the deposition of the capping clay layer, created
anaerobic conditions in the freshwater swamp interval, and isolated
it hydrologically from the rest of the sediment column. The subsequent
infiltration of marine water into this organic material led to sulfate
reduction, the buildup of H2S and FeS, and anoxic conditions.
Continued sulfidation eventually resulted in euxinic conditions, as
evidenced by elevated levels of Fe, S, and especially Mo, the diagnostic
marker of euxinia. Because this chemical transformation occurred long
after the original deposition the geochemical signature does not reflect
soil chemistry at the time of deposition and cannot be used to infer
syn-depositional environmental conditions, emphasizing the importance
of recognizing diagenetic processes in paleoenvironmental studies.