A “bottle-around-ship” like method synthesized yolk-shell Ag3PO4@MIL-53(Fe) Z-scheme photocatalysts for enhanced tetracycline removal

Li, Xiaopei; Zeng, Zhuotong; Zeng, Guangming; Wang, Dongbo; Xiao, Rong; Wang, Yingrong; Zhou, Chenyun; Yi, Huan; Ye, Shujing; Yang, Yang; Xiong, Weiping

doi:10.1016/j.jcis.2019.11.025

Cited by 77 publications

(15 citation statements)

References 70 publications

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“…Similarly, Fe 4+ ions are also reduced to Fe 3+ ions by releasing electrons, while the hydroxyl groups on the surface of Fe–BiOI-In can translate into hydroxyl radicals ( • OH). Thus, the active species (h*, OH, and O 2 ) can join in the oxidation of TC and finally produce CO 2 , H 2 O, and so forth. − Therefore, the synthesized Fe–BiOI-In has been the potential ability for the photocatalytic degradation of TC.…”

Section: Resultsmentioning

confidence: 99%

Strategic Doping Approach of the Fe–BiOI Microstructure: An Improved Photodegradation Efficiency of Tetracycline

et al. 2021

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The present study describes the strategic doping of Fe metal ions into a BiOI microstructure using ex situ and in situ processes to synthesize a Fe−BiOI microstructure and their effect on photocatalytic degradation of tetracycline (TC). The data suggested that in situ Fe−BiOI (Fe−BiOI-In) has superior performance compared to ex situ Fe−BiOI (Fe−BiOI-Ex) due to the uniform dispersion of Fe within the Fe−BiOI material. Calculated bandgaps ∼1.8, ∼1.5, and 2.4 eV were observed for BiOI (without Fe), Fe−BiOI-In, and Fe−BiOI-Ex, respectively. Interestingly, Fe incorporation within BiOI might decrease the bandgap in Fe−BiOI-In due to the uniform distribution of metal ions, whereas increasing the bandgap in Fe−BiOI-Ex attributed to nonuniform distribution or agglomeration of metal ions. The uniform dispersion of Fe within Fe−BiOI modulates electronic properties as well as increases the exposure of Fe ions with TC, thereby higher degradation efficiency of TC. The in situ Fe−BiOI material shows 67 and 100% degradation of TC at 10 and 1 mg/L, respectively. The TC degradation was also found to be pH-dependent; when increasing the pH value up to 10, 94% degradation was achieved at 10 mg/L within 60 min of solar irradiation. The analysis was also performed over BiOI, which proves that Fe has a profound effect on TC degradation as Fe(II) tends to trigger oxidation−reduction by utilizing the chelate formation tendency of TC. Therefore, the prepared Fe−BiOI-In has the potential ability to degrade pharmaceutical compounds, especially, TC from wastewater.

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Section: Resultsmentioning

confidence: 99%

Strategic Doping Approach of the Fe–BiOI Microstructure: An Improved Photodegradation Efficiency of Tetracycline

et al. 2021

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“…A novel yolk-shell Ag 3 PO 4 @MIL-53(Fe) Z-scheme photocatalyst was fabricated by Li et al [188] and experimental results showed that TC removal efficiency is about 95.18 % almost 3 times more than that of MIL-53(Fe). BET results depict improved surface area for the composite, attributed to the introduction of Ag 3 PO 4 and the total pore volume of MIL-53(Fe) was observed as 0.024 cm3/g, which had further, improved to 0.341 cm3/gAg 3 PO 4 cores after the introduction of core Ag 3 PO 4 .…”

Section: Mof Based Heterostructurementioning

confidence: 99%

“…BET results depict improved surface area for the composite, attributed to the introduction of Ag 3 PO 4 and the total pore volume of MIL-53(Fe) was observed as 0.024 cm3/g, which had further, improved to 0.341 cm3/gAg 3 PO 4 cores after the introduction of core Ag 3 PO 4 . [188] Sun et al [189] reported ternary heterojunctions MWCNT/N-TiO 2 /UiO-66-NH 2 , synthesized by in-situ solvothermal-hydrothermal approach for degradation of KPF in 120 min reaction time. The MWCNT/N-TiO 2 was synthesized via solvothermal technique followed by MOF attachment using the hydrothermal method.…”

Section: Mof Based Heterostructurementioning

confidence: 99%

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Advancement towards Antibiotic Remediation: Heterostructure and Composite materials

2021

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Today's world is on the verge of antibiotic pollution by humans, veterinary therapeutics polluting our water body, and on account of the scarcity in advanced water treatment techniques in the wastewater treatment plants (WWTPs). It is of enormous importance to have an insight into various kinds of antibiotics and their attributes. The primary aspects of antimicrobial resistance caused by antibiotic pollution in the environment have been briefly enlightened. Here the nature and occurrence of antibiotics accumulation in the environment and a world pollution scenario have been illustrated. Adsorption and photocatalysis are the most standard techniques used for remediation. The well‐known nano photocatalyst heterostructure materials Titanium dioxide (TiO2), bismuth (Bi) materials are also utilized as the main frame materials for the composites and heterostructures. Alternatively, the porous carbon‐based materials and metal‐organic framework (MOF) materialsare entitled to their excellent adsorption capability. This review portrays comprehensive insight into the advances and breakthroughs made so far by different heterostructures and nanocomposite materials for antibiotics removal and provides a road map to future researchers towards a more efficient water treatment system.

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“…According to the works listed in the references, an MIL-53(Fe)&Ag 3 PO 4 (MFA) composite has been successfully synthesized to improve the photocatalytic activity. 18–20 Nevertheless, several problems remain with the current MFA composite, such as low specific surface area, insufficient activity, narrow application, and poor stability. Therefore, in this work, novel MIL-53(Fe)/Ag 3 PO 4 /Ag (MFAA) composites were prepared through an electrostatic adsorption method.…”

Section: Introductionmentioning

confidence: 99%

Fabrication of MIL-53(Fe)/Ag₃PO₄ cooperative photoreduction of Ag⁰ particles with outstanding efficiency for photodriven H₂ evolution and pollutant degradation

Zeng

Zhang

et al. 2022

React. Chem. Eng.

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A “bottle-around-ship” like method synthesized yolk-shell Ag3PO4@MIL-53(Fe) Z-scheme photocatalysts for enhanced tetracycline removal

Cited by 77 publications

References 70 publications

Strategic Doping Approach of the Fe–BiOI Microstructure: An Improved Photodegradation Efficiency of Tetracycline

Strategic Doping Approach of the Fe–BiOI Microstructure: An Improved Photodegradation Efficiency of Tetracycline

Advancement towards Antibiotic Remediation: Heterostructure and Composite materials

Fabrication of MIL-53(Fe)/Ag₃PO₄ cooperative photoreduction of Ag⁰ particles with outstanding efficiency for photodriven H₂ evolution and pollutant degradation

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A “bottle-around-ship” like method synthesized yolk-shell Ag3PO4@MIL-53(Fe) Z-scheme photocatalysts for enhanced tetracycline removal

Cited by 77 publications

References 70 publications

Strategic Doping Approach of the Fe–BiOI Microstructure: An Improved Photodegradation Efficiency of Tetracycline

Strategic Doping Approach of the Fe–BiOI Microstructure: An Improved Photodegradation Efficiency of Tetracycline

Advancement towards Antibiotic Remediation: Heterostructure and Composite materials

Fabrication of MIL-53(Fe)/Ag3PO4 cooperative photoreduction of Ag0 particles with outstanding efficiency for photodriven H2 evolution and pollutant degradation

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Fabrication of MIL-53(Fe)/Ag₃PO₄ cooperative photoreduction of Ag⁰ particles with outstanding efficiency for photodriven H₂ evolution and pollutant degradation