“…Considering the serious global warming problem, the discovery of a solar energyconverting material in the Vis-NIR domain for optoelectronic devices, such as photodetectors, light emission devices, sensors, and dye-sensitized solar cells, has occurred [1][2][3][4][5]. Among the nanoarchitecture nanomaterials, the [M6L i 8L a 6] ncluster unit, composed of a central Mo6 cluster, eight inner ligands at the face-capping position (L i = halogen or chalcogen; i for inner), and six apical ligands at the terminal positions ( L a = halogen, OH -, H2O, N3, OCOCnH2n+1, etc; a for apical.…”