A calix[4]arene derivative-doped perchlorate-selective membrane electrodes with/without multi-walled carbon nanotubes

Ertürün, H. Elif Kormalı; Özel, Ayça Demirel; Ayanoğlu, Melek Nur; Şahin, Özlem

doi:10.1007/s11581-016-1906-8

Cited by 10 publications

(6 citation statements)

References 64 publications

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“…The selectivity of ISE with ISM towards sulphate, nitrate and chloride is also high (Figure 5), which is especially important for the analysis of mineral water samples. In addition, the nitrate anion is often an interfering anion for many perchlorate-ISEs described in literature [40][41][42][43][44][45][46][47][48][49][50][51][52][53][54][55][56][57]. To shed light on the exchange reaction mechanism of perchlorate-ISEs with BBU ionophore, the correlation of selectivity coefficients with equilibrium constants of the {X − @BBU} complex was evaluated (Figure 6).…”

Section: Selectivity Of Perchlorate Sc-isementioning

confidence: 99%

“…Such ion associates (ion exchangers) are also employed in ion-selective electrodes (ISEs) [30][31][32][33][34][35][36][37][38][39]. Potentiometric determination of perchlorate concentration by ISEs is very popular [39][40][41][42][43][44][45][46][47][48][49][50][51][52][53][54][55][56][57] because it enables the determination of the concentration in a broad concentration range (−log [ClO 4 − ] = 1-5) with simple instrumentation. There are also some attempts to enlarge the concentration range by lowering the limit of detection (LOD) for the perchlorate ion using a special methodology [37][38][39] or selective receptors, e.g., calixarenes [54][55][56], macrocyclic ligands and their metal complexes [42][43][44]48,49,53].…”

Section: Introductionmentioning

confidence: 99%

“…Potentiometric determination of perchlorate concentration by ISEs is very popular [39][40][41][42][43][44][45][46][47][48][49][50][51][52][53][54][55][56][57] because it enables the determination of the concentration in a broad concentration range (−log [ClO 4 − ] = 1-5) with simple instrumentation. There are also some attempts to enlarge the concentration range by lowering the limit of detection (LOD) for the perchlorate ion using a special methodology [37][38][39] or selective receptors, e.g., calixarenes [54][55][56], macrocyclic ligands and their metal complexes [42][43][44]48,49,53]. In addition, miniaturized ISEs and ISFETs could be utilized for the determination of perchlorate concentration in on-line flow mode (e.g., chromatography [9], FIA [52]), when the ISE shows a fast response and a long lifetime.…”

Section: Introductionmentioning

confidence: 99%

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Perchlorate Solid-Contact Ion-Selective Electrode Based on Dodecabenzylbambus[6]uril

et al. 2022

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Dodecabenzylbambus[6]uril (Bn12BU[6]) is an anion receptor that binds the perchlorate ion the most tightly (stability constant ~1010 M−1) of all anions due to the excellent match between the ion size in relation to the receptor cavity. This new bambusuril compound was used as an ionophore in the ion-selective membrane (ISM) to develop ion selective electrodes (ISEs) for determination of perchlorate concentration utilizing the poly(3,4-ethylenedioxythiophene) (PEDOT) polymer film as a solid-contact material. Variation of the content of Bn12BU[6] and tridodecylmethylammonium chloride (TDMACl) in the plasticized poly(vinyl chloride)-based ISM was also tested. All the prepared solid-contact ISEs and their analytical performance were characterized by potentiometry, cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS) and chronopotentiometry. The ISEs showed rapid response and a sub-Nernstian slope (~57 mV/decade) during potentiometric measurements in perchlorate solutions in the concentration range from 10−1 to 10−6 M simultaneously with their high stability and sufficient selectivity to other common inorganic anions like bromide, chloride, nitrate and sulphate. The function of the ISE was further verified by analysis of real water samples (lake, sea, and mineral water), which gave accurate and precise results.

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Section: Selectivity Of Perchlorate Sc-isementioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

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Perchlorate Solid-Contact Ion-Selective Electrode Based on Dodecabenzylbambus[6]uril

et al. 2022

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“…It was found to be selectively responsive towards the perchlorate ions in micro molar range with an advantage over response time and lifetime. [124] Billing et al has reported a nano-hybrid based on CNT and Pyrene ring, where both the elements are π-π stacked to each other through aromatic rings. The developed nano-hybrid has detected nitrate ions with limit of detection found to be 8.1 nM.…”

Section: Recognition Of Anionsmentioning

confidence: 99%

Carbon Nanotubes and its Potential Application in Sensing

Billing

2021

ChemistrySelect

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This study provides overview of the different type of nanomaterials depending upon their size, and type, however focusing more on the Carbon Nanotubes. This review highlights the different synthesis and purification techniques and also the functionalization methods of Carbon Nanotubes (CNTs). In particular, molecular recognition application of Carbon Nanotubes is explored in the present study. The majority of data was collected for optical and electrochemical studies of Carbon Nanotube based platform for the detection of metal ions, anions, nitroaromatics, biomolecules and gas molecules since last two decades. This review ends with an outlook of future perspectives that could be employed in nano sensor fabrication. I believe this review will act as a road map to guide the new researchers towards the concept of nanofabrication that can be employed to develop Carbon Nanotube based platform for sensing applications.

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“… 7 IC was applied by Sungur and Sangün in a wide variety of complex matrices such as soil, water, milk, fish, vegetables and fruits with LOD values between 0.24 and 0.59 μg/kg. 8 For perchlorate determination, there are methodologies such as IC-tandem mass spectrometry, 9 , 10 liquid chromatography-tandem mass spectrometry, 11 , 12 and the ion selective electrode 13 method also existing in the literature.…”

Section: Introductionmentioning

confidence: 99%

Ionic Liquid-Modified Gold Nanoparticle-Based Colorimetric Sensor for Perchlorate Detection via Anion−π Interaction

2022

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A rapid and convenient nanoparticle(NP)-based colorimetric sensor was developed for determining the propellant oxidant, ammonium perchlorate (AP). The sensing element was manufactured by modifying gold nanoparticles (AuNPs) with [(1-methyl-1 H -imidazol-2-yl)sulfanyl]acetic acid, which is an imidazolium-based ionic liquid (IL), to produce the IL@AuNP nanosensor stabilized by polyvinylpyrrolidone. The used IL is an exceptional IL which can attach to AuNPs through the sulfanyl-S atom. The sensing principle was based on observing the red shift in the surface plasmon resonance band of AuNPs leading to NP aggregation as a result of anion−π interaction of perchlorate anion with the zwitterionic form of IL@AuNPs so as to bring opposite charges face-to-face, thereby reducing the overall surface charge of NPs. The surface plasmon resonance band of AuNPs at 540 nm shifted to 700 nm as a result of aggregation. The ratiometric sensing was performed by dividing the absorbance at 700 nm to the absorbance at 540 nm and correlating this ratio to the AP concentration. The limit of detection and limit of quantification of the sensor for AP were 1.50 and 4.95 μM, respectively. Possible interferences of other energetic substances and common soil ions in synthetic mixtures were also investigated to achieve acceptable recoveries of analyte. This work may pioneer similar sensing systems where the overall anionic charges of IL-functionalized AuNPs are exceptionally reduced by an analyte anion (perchlorate), thereby forcing NPs to aggregate.

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A calix[4]arene derivative-doped perchlorate-selective membrane electrodes with/without multi-walled carbon nanotubes

Cited by 10 publications

References 64 publications

Perchlorate Solid-Contact Ion-Selective Electrode Based on Dodecabenzylbambus[6]uril

Perchlorate Solid-Contact Ion-Selective Electrode Based on Dodecabenzylbambus[6]uril

Carbon Nanotubes and its Potential Application in Sensing

Ionic Liquid-Modified Gold Nanoparticle-Based Colorimetric Sensor for Perchlorate Detection via Anion−π Interaction

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