A click derived triazole-coumarin derivative as fluorescence on-off PET based sensor for Ca2+and Fe3+ ions

Puthiyedath, Thasnim; Bahulayan, D.

doi:10.1016/j.snb.2018.05.126

Cited by 50 publications

(16 citation statements)

References 34 publications

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“…The most functional calcium-sensitive fluorescent sensors are ratiometric probes with dual excitation wavelengths based on fluorescein or rhodamine dye derivatives. , However, these ratiometric calcium-sensitive sensors suffer from some disadvantages such as their homogeneity and excitation in the UV region . Other calcium-sensitive fluorescent probes are reported based on homogeneous indicators such as coumarin and its derivatives, spiropyran photochromic compounds, , with the same disadvantages that were mentioned above.…”

Section: Resultsmentioning

confidence: 99%

Sensitive Ratiometric Fluorescent Metal-Organic Framework Sensor for Calcium Signaling in Human Blood Ionic Concentration Media

Bagheri

Masoomi

2020

ACS Appl. Mater. Interfaces

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A two-dimensional fluorescent metal-organic framework (MOF) sensor, TMU-5S, was synthesized by introducing rhodamine B into the framework of TMU-5. This dye-sensitized MOF was explored as a ratiometric fluorescent sensor for Ca2+ signaling in the presence of interfering cations in ionic concentrations similar to that of blood plasma that exhibits exceptional sensitivity and selectivity to Ca2+ and faster response and recovery times than any other reported fluorescent sensor. This can be attributed to strong electrostatic interactions between basic azine groups in the narrow pore walls of TMU-5S and Ca2+ as hard–hard acid–base interactions. The results show that the two-dimensional signal transduction can reduce interfering responses from the environment and thus create exceptional sensitivity.

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Section: Resultsmentioning

confidence: 99%

Sensitive Ratiometric Fluorescent Metal-Organic Framework Sensor for Calcium Signaling in Human Blood Ionic Concentration Media

Bagheri

Masoomi

2020

ACS Appl. Mater. Interfaces

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“…Selective fluorescent coumarin-triazole chemosensor 11 toward Ca 2+ and Fe 3+ ions was synthesized [39]. Calcium(II) plays an important role in bone formation and as a second messenger in neurotransmitter release from neurons, in contraction of all muscle cell types and in fertilization.…”

Section: Sensing Of Multiple Metal Cationsmentioning

confidence: 99%

Fluorogenic Polyfunctional Coumarin-Based Chemosensors for Multianalyte Detection

Дубоносов¹,

Breń²

2020

Fluorescence Methods for Investigation of Living Cells and Microorganisms

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Fluorogenic sensors capable of selective interaction with analyte, which leads to a change in the position or intensity of the fluorescence band, allow to detect ions or molecules in situ and in vivo and possess high sensitivity and efficiency. Currently, they are widely used in organic, biological, and medical chemistry and environmental sciences for express monitoring of the ionic composition of the medium. They represent a serious alternative to the bulky, expensive, non-transportable technical devices traditionally used for this purpose, such as atomic absorption, atomic emission, and XRF spectrometers. Polyfunctional sensors capable of independent detection of two or more kinds of "guests" from a multiple mixture of cations, anions, or molecules due to specific spectral responses via the same or different channels constitute a rapidly developing area of chemosensory science. This specific feature is associated with the presence of two or more coordination centers in their molecules, or the capability of one center to selectively respond to various analytes with individual spectral changes. Coumarin (2H-chromene-2-one) core is one of the most versatile frameworks for the design of fluorogenic polyfunctional chemosensors for multianalyte detection. In this chapter, we report on the review of sensing properties of this group of chemosensors based on functionalized coumarin derivatives, including their applications in bioimaging.

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“…Fluorescent sensors based on small molecules, in particular, have significant advantages such as their exquisite and noninvasive size, high sensitivity, selectivity, and fast response time. To date, numerous fluorescent Hg 2+ ( Chen, et al, 2015 ; Kim, et al, 2012 ) probes have been reported based on varieties of fluorophore like Rhodamine ( Bera, et al, 2014 ; Chang, et al, 2018 ; Su, et al, 2017 ; Tang, et al, 2017 ; Zhao, et al, 2010 ), BODIPY ( Hatai, et al, 2012 ; Lu, et al, 2009 ; Yoon, et al, 2005 ), Coumarin ( Sie, et al, 2017 ; Puthiyedath and Bahulayan, 2018 ), Schiff base ( Chen, et al, 2018 ; Duan, et al, 2019 ; Sarkar, et al, 2016 ; Wang, et al, 2018b ; Wang, et al, 2018d ; Zhang, et al, 2017 ), AIE luminophore ( Chen, et al, 2017 ; Selvaraj, et al, 2021 ; Wang, et al, 2018a ), Peptide-based benzoxazole unit ( Oliveira, et al, 2011 ; Oliveira, et al, 2013 ), etc. These probes were usually prepared either through the complexation with the multiple binding sites or through a chemical reaction with the proper functional group onto fluorescent molecules.…”

Section: Introductionmentioning

confidence: 99%

Design and Synthesis of Dipeptidomimetic Isocyanonaphthalene as Enhanced-Fluorescent Chemodosimeter for Sensing Mercury Ion and Living Cells

Wang

Cheng

et al. 2022

Front. Chem.

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A novel valine-based isocyanonaphthalene (NpI) was designed and synthesized by using an easy method and enabled the selective fluorescence detection of Hg2+. The chemodosimeter can display an immediate turn-on fluorescence response (500-fold) towards target metal ions upon the Hg2+-mediated conversion of isocyano to amino within NpI. Based on this specific reaction, the fluorescence-enhancement probe revealed a high sensitivity toward Hg2+ over other common metal ions and exhibited excellent aqueous solubility, good antijamming capability, high sensitivity (detection limit: 14.2 nM), and real-time detection. The response mechanism of NpI was supported by NMR spectroscopy, MS analysis and DFT theoretical calculation using various techniques. Moreover, a dipeptidomimetic NpI probe was successfully applied to visualize intracellular Hg2+ in living cells and monitor Hg2+ in real water samples with good recoveries and small relative standard deviations.

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A click derived triazole-coumarin derivative as fluorescence on-off PET based sensor for Ca2+and Fe3+ ions

Cited by 50 publications

References 34 publications

Sensitive Ratiometric Fluorescent Metal-Organic Framework Sensor for Calcium Signaling in Human Blood Ionic Concentration Media

Sensitive Ratiometric Fluorescent Metal-Organic Framework Sensor for Calcium Signaling in Human Blood Ionic Concentration Media

Fluorogenic Polyfunctional Coumarin-Based Chemosensors for Multianalyte Detection

Design and Synthesis of Dipeptidomimetic Isocyanonaphthalene as Enhanced-Fluorescent Chemodosimeter for Sensing Mercury Ion and Living Cells

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