BACKGROUND: Removal of recalcitrant chemicals is an essential step in conventional wastewater treatment plants. Among these, pesticides are of great environmental concern. Different treatment options were compared in this work: the combination of advanced oxidation processes (AOPs) with biological treatment, an aerobic process and anaerobic biological treatments. The role of chemical processes in improving solution biodegradability was verified. Oxidation by-products were identified and biological process kinetics are reported. The performance of biological processes and their kinetics were studied.