A comparative experimental and density functional study of glucose adsorption and electrooxidation on the Au-graphene and Pt-graphene electrodes

Çağlar, Aykut; Düzenli, Derya; Önal, Işık; Tezsevin, Ilker; Şahin, Özlem; Kıvrak, Hilal

doi:10.1016/j.ijhydene.2019.10.163

Cited by 49 publications

(20 citation statements)

References 44 publications

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“…The Bromide Anion Exchange (BAE) method was reported for the preparation of metallic nanocatalysts onto a Vulcan substrate [37]. More conductive material such as graphene layer was used as substrate for electrodepositing Au and Pt nanocatalysts for glucose oxidation [38]. BAE method was also performed to disseminate catalysts nanoparticles on reduced graphene oxide (rGO) [39].…”

Section: Introductionmentioning

confidence: 99%

New insights on the selective electroconversion of the cellulosic biomass-derived glucose at PtAu nanocatalysts in an anion exchange membrane fuel cell

Lemoine

Holade²,

Dubois³

et al. 2021

Journal of Electroanalytical Chemistry

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Section: Introductionmentioning

confidence: 99%

New insights on the selective electroconversion of the cellulosic biomass-derived glucose at PtAu nanocatalysts in an anion exchange membrane fuel cell

Lemoine

Holade²,

Dubois³

et al. 2021

Journal of Electroanalytical Chemistry

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“…Finally, combined fuel cells, known as fuel piles, have wide applications in a variety of fields, such as space crafts, reconnaissance drones, discovery submarines, hybrid cars, and fuel pile power plants. [3][4][5][6][7][8][9] In contrast with these advantages, the major problem with fuel cells is that the cell's reaction rate is typically low and virtually useless under normal conditions. Thus, since the introduction of fuel cells, many researchers, including Denaley et al, have tried to find the effective ways to enhance the fuel cells' reaction rate.…”

Section: Introductionmentioning

confidence: 99%

Theoretical study of activation of O₂ at cathode and CH₃OH at anode of “CH₃OH ‐O₂” fuel cell using ZnC₄H₄ and CuC₄H₄ organometallic catalysts “a DFT study”

Rahnama

Aghaie

Noei

et al. 2021

J Chinese Chemical Soc

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Studying the interaction of oxygen molecule with organometallic compounds as low cost catalysts have always been an interesting research subject. So, in this study, the catalytic effect of TM-C 4 H 4 organometallic compounds (TM is Zn or Cu) was investigated to enhance the reaction rate of "methanol-oxygen" fuel cell using density functional theory(DFT) calculations at the B3LYP level and the basis set of 6-31G(d). In addition, the gap energy (E g ) for each of TM-C 4 H 4 and the adsorption energy(E ad ) of each pair of TM-C 4 H 4 /O 2 and TM-C 4 H 4 /CH3OH were calculated. Natural bond orbital (NBO) calculations were also performed to examine the charge transfer and bond stability. The results showed that, due to the adsorption process, the bond length of O=O increased about 16 and 20%, respectively, while the C and O distance in the CH 3 OH was increased by 137 and 199%, respectively. These rises are fairly due to the somewhat negative charge transfer from the organometallic compound to O 2 or C-O in methanol. A bond elongation increases the chemical activity and reactivity of the reactants at the anode and the cathode of the studied fuel cell. The results showed that, ZnC 4 H 4 activates O 2 and CH 3 OH in the "CH 3 OH-O 2 " fuel cell reaction more than the CuC 4 H 4 compound.

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“…FCs, which convert chemical energy into electrical energy, are environmentally friendly, long-lasting technology that does not harm nature. 19 Direct liquid-fed FCs (DLFCs), employing fluid fuels such as methanol, 67,68 glucose, 22,69 hydrazine, 70 ethanol, 11,71 glycerol, 72 ethylene glycol, 73,74 and formic acid (HCOOH, FA), 23,75 are preferable because DLFCs do not have the disadvantages of hydrogen FCs like employing a pure gas tank or fuel reforming. 76,77 FA is a preferred and promising fuel due to its advantages such as portable, low cost, clean liquid fuel.…”

Section: Introductionmentioning

confidence: 99%

The preparation, characterization, and electrooxidation of colloidal palladium modified poly(methacrylic acid) hydrogel as formic acid fuel cell anode catalyst

et al. 2021

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At present, poly(methacrylic acid) (MA), poly(MA) hydrogel, and Pd-doped poly(MA) hydrogel modified electrodes are constructed on graphite pencil (G).The Pd precursor is coated on the poly(MA)/G electrodes surface using the electrodeposition method. These electrodes are characterized by thermogravimetric analysis (TGA), Fourier transform infrared spectroscopy, and scanning electron microscopy-energy dispersive X-ray. Poly(MA) hydrogel and Pd-doped poly(MA) hydrogel are successfully prepared by the polymerization and further electrodeposition. Formic acid electro-oxidation (FAEO) activities are examined with cyclic voltammetry (CV), chronoamperometry (CA), and electrochemical impedance spectroscopy (EIS). Poly(MA)/G and Pd doped poly(MA) electrodes exhibit promising electro-catalytic activity with 60 mA current density, greater than literature values. Pd-doped poly(MA) hydrogel electrodes are promising electrodes for FAEO.

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A comparative experimental and density functional study of glucose adsorption and electrooxidation on the Au-graphene and Pt-graphene electrodes

Cited by 49 publications

References 44 publications

New insights on the selective electroconversion of the cellulosic biomass-derived glucose at PtAu nanocatalysts in an anion exchange membrane fuel cell

New insights on the selective electroconversion of the cellulosic biomass-derived glucose at PtAu nanocatalysts in an anion exchange membrane fuel cell

Theoretical study of activation of O₂ at cathode and CH₃OH at anode of “CH₃OH ‐O₂” fuel cell using ZnC₄H₄ and CuC₄H₄ organometallic catalysts “a DFT study”

The preparation, characterization, and electrooxidation of colloidal palladium modified poly(methacrylic acid) hydrogel as formic acid fuel cell anode catalyst

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A comparative experimental and density functional study of glucose adsorption and electrooxidation on the Au-graphene and Pt-graphene electrodes

Cited by 49 publications

References 44 publications

New insights on the selective electroconversion of the cellulosic biomass-derived glucose at PtAu nanocatalysts in an anion exchange membrane fuel cell

New insights on the selective electroconversion of the cellulosic biomass-derived glucose at PtAu nanocatalysts in an anion exchange membrane fuel cell

Theoretical study of activation of O2 at cathode and CH3OH at anode of “CH3OH ‐O2” fuel cell using ZnC4H4 and CuC4H4 organometallic catalysts “a DFT study”

The preparation, characterization, and electrooxidation of colloidal palladium modified poly(methacrylic acid) hydrogel as formic acid fuel cell anode catalyst

Contact Info

Product

Resources

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Theoretical study of activation of O₂ at cathode and CH₃OH at anode of “CH₃OH ‐O₂” fuel cell using ZnC₄H₄ and CuC₄H₄ organometallic catalysts “a DFT study”