Sorption behaviour of four organophosphorus pesticides: demeton-S-methyl, methidathion, azinphosmethyl and phosalone, in two different pond sediments is reported. The sorption coefficients K d in both sediments are found to follow the same sequence as the lipophilicity of the compounds expressed as their noctanol/water partition coefficients, K ow . The isotherms for demeton-S-methyl and methidathion are approximately linear in the concentration range studied, whereas nonlinear Freundlich isotherm with parameter 1/n significantly less than 1 better fits the experimental data for azinphos-methyl and phosalone. The sorption efficiency for all the four pesticides is higher in the sediment with a lower content of organic matter. Isotherm nonlinearities and discrepancy between K d values and the organic matter content of the sediments both indicate that a simple partition model does not offer indiscriminately an adequate visualization of the sorption behaviour. However, the sorption and partition results reported here are in a good agreement with literature data for a series of eighteen organophosphorus pesticides. This is demonstrated by testing the consistency of the results with the respective literature data in Collander equations relating in log-log linear regressions K ow and organic matter sorption coefficients, K om , to water solubilities of organophosphorus pesticides.