Carbon perovskite
solar cells (C-PSCs), using carbon-based counter
electrodes (C-CEs), promise to mitigate instability issues while providing
solution-processed and low-cost device configurations. In this work,
we report the fabrication and characterization of efficient paintable
C-PSCs obtained by depositing a low-temperature-processed graphene-based
carbon paste atop prototypical mesoscopic and planar n–i–p
structures. Small-area (0.09 cm
2
) mesoscopic C-PSCs reach
a power conversion efficiency (PCE) of 15.81% while showing an improved
thermal stability under the ISOS-D-2 protocol compared to the reference
devices based on Au CEs. The proposed graphene-based C-CEs are applied
to large-area (1 cm
2
) mesoscopic devices and low-temperature-processed
planar n–i–p devices, reaching PCEs of 13.85 and 14.06%,
respectively. To the best of our knowledge, these PCE values are among
the highest reported for large-area C-PSCs in the absence of back-contact
metallization or additional stacked conductive components or a thermally
evaporated barrier layer between the charge-transporting layer and
the C-CE (strategies commonly used for the record-high efficiency
C-PSCs). In addition, we report a proof-of-concept of metallized miniwafer-like
area C-PSCs (substrate area = 6.76 cm
2
, aperture area =
4.00 cm
2
), reaching a PCE on active area of 13.86% and
a record-high PCE on aperture area of 12.10%, proving the metallization
compatibility with our C-PSCs. Monolithic wafer-like area C-PSCs can
be feasible all-solution-processed configurations, more reliable than
prototypical perovskite solar (mini)modules based on the serial connection
of subcells, since they mitigate hysteresis-induced performance losses
and hot-spot-induced irreversible material damage caused by reverse
biases.