Soil moisture (SM) plays a critical role in various fields such as agriculture, hydrology, and land-atmosphere interactions. Despite numerous studies investigating SM inversion using ensemble learning and microwave remote sensing, the optimal method remains uncertain. This study aims to evaluate the performance of the categorical boosting algorithm (CatBoost) in comparison to other multiple-boosting algorithms for SM prediction. Special emphasis is given to feature selection in a vegetation-covered area based on remote sensing imagery. Appropriate feature selection is vital for achieving accurate predictions, and this study focuses on identifying relevant features and assessing CatBoost's suitability for the task. The study incorporates several boosting algorithms including Gradient Boosting Decision Tree (GBDT), Extreme Gradient Boosting (XGBoost), Light Gradient Boosting Machine (LightGBM), and CatBoost to estimate SM. Results indicate that radar backscatter coefficient, soil roughness, and digital elevation model (DEM) are crucial features for SM retrieval. Comparatively, CatBoost outperforms GBDT, XGBoost, and LightGBM in various feature combinations. The most favorable results are obtained when utilizing all features as inputs for the algorithm. These optimal results yield a mean absolute error (MAE) of 2.40 vol.%, mean relative error (MRE) of 0.16 vol.%, root mean square error (RMSE) of 3.26 vol.%, and Pearson correlation coefficient of 0.73. Additionally, the study analyzes the inversion results for different ranges of SM and Normalized Difference Vegetation Index (NDVI). Within the range of SM from 0 to 25 vol.% and NDVI from 0 to 0.7, utilizing all features yields the most accurate results.