“…As device down-scaling, however, physical vapor deposition, typically used for metal deposition, suffers from poor step coverage in high aspect ratio contact holes. 8,9) Therefore, ALD Ni is required for nanoscale device contact because ALD has excellent conformality and compatibility to current Si unit process. 10) Until now, although several studies on Ni ALD have been performed, they have showed limitations such as complex process, low purity, and low growth rate.…”