A cost‐effective shortcut to prepare organoselenium catalysts via decarboxylative coupling of phenylacetic acid with elemental selenium

Cao, Huaqiang; Liu, Mingxuan; Qian, Rongrong; Zhang, Xu; Yu, Lei

doi:10.1002/aoc.4599

Cited by 20 publications

(7 citation statements)

References 62 publications

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“…Various strategies are adopted to obtain catalytically relevant organosulphur and organoselenium ligands of various types including thioethers, selenoethers, Schiff bases, pincer ligands, carbene precursors and esters. [166][167][168][169][170][171][172][173] In the majority of such ligands, the sulphur and selenium donor site remain present as C-S-C or C-Se-C. The strategies used to obtain such interesting ligand frameworks are discussed under this sub-section.…”

Section: Important Strategies For Synthesismentioning

confidence: 99%

Organosulphur and organoselenium compounds as emerging building blocks for catalytic systems forO-arylation of phenols, a C–O coupling reaction

et al. 2022

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Section: Important Strategies For Synthesismentioning

confidence: 99%

Organosulphur and organoselenium compounds as emerging building blocks for catalytic systems forO-arylation of phenols, a C–O coupling reaction

et al. 2022

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“…Also, diselenide synthesis was purposed by decarboxylative coupling of phenylacetic acid with selenium powder, potential alternative to otherwise frequently employed methods with transition metal or hazardous chemicals like Grignard reagent [175] …”

Section: Overview On Selenium‐catalyzed/selenium Incorporating Transfmentioning

confidence: 99%

Insights into the Recent Synthetic Advances of Organoselenium Compounds

2021

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The ever-growing interest for organoselenium compounds amongst the chemists has made commendable impact in the field of medicinal chemistry, material chemistry, chemical biology and biochemistry. Researchers have progressively contributed in the development of organoselenium compounds over the years which has been periodically reviewed. On the similar note, this review attempts at providing an overview of the recent advances made in organoselenium chemistry while covering their catalytic indulgence in different transformational approaches, their role in asymmetric synthesis, and synthetic approaches steering their synthesis. These approaches encompass selenofunctionalization and/or cyclization, electrochemical selenylation, bromolactonization, [2,3]-or [1,2]-sigmatropic rearrangement reactions among others. Herein, we have focused on the synthetic approaches developed for the past three years that have not been covered in previously reviewed scientific material. With the knowledge of the recent progress covered, this review could contribute towards future development of organoselenium compounds along with the improvement of the current status.

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“…In 2018, Yu and co‐workers [16] disclosed a decarboxylative coupling reaction of phenylacetic acid and elemental selenium for the synthesis of a mixture of symmetrical dibenzyl diselenide and dibenzyl selenide ( 5 ) (Scheme 5a). The addition of hydroquinone resulted in no formation of the desired product, supporting a radical way.…”

Section: Synthesis Of Organoselenium Compounds With Elemental Seleniummentioning

confidence: 99%

Synthesis of Organoselenium Compounds with Elemental Selenium

Liu

Zhou

et al. 2021

Adv Synth Catal

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In the recent decade, growing efforts have been devoted to employing elemental selenium as a selenium source in organic synthesis. In contrast to unstable, smelly, and toxic previous selenium reagents, elemental selenium is readily available, cheap, bench-stable, and easy to handle. This review will mainly focus on the strategies for the activation of elemental selenium and the synthesis of organoselenium compounds including monoselenides, diselenides, selenium-containing heterocycles and so on. The Synthesis ofMonoselenides with Elemental Selenium 2.2. The Synthesis of Diselenides with Elemental Selenium 2.3. The Synthesis of Selenium-Containing Heterocycles with Elemental Selenium 2.4. The Synthesis of Other Organoselenium Compounds with Elemental Selenium 3. Conclusions

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A cost‐effective shortcut to prepare organoselenium catalysts via decarboxylative coupling of phenylacetic acid with elemental selenium

Cited by 20 publications

References 62 publications

Organosulphur and organoselenium compounds as emerging building blocks for catalytic systems forO-arylation of phenols, a C–O coupling reaction

Organosulphur and organoselenium compounds as emerging building blocks for catalytic systems forO-arylation of phenols, a C–O coupling reaction

Insights into the Recent Synthetic Advances of Organoselenium Compounds

Synthesis of Organoselenium Compounds with Elemental Selenium

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