An advanced Thomson scattering system has been built for a linear plasma generator for plasma surface interaction studies. The Thomson scattering system is based on a Nd:YAG laser operating at the second harmonic and a detection branch featuring a high etendue (f /3) transmission grating spectrometer equipped with an intensified charged coupled device camera. The system is able to measure electron density (n e ) and temperature (T e ) profiles close to the output of the plasma source and, at a distance of 1.25 m, just in front of a target. The detection system enables to measure 50 spatial channels of about 2 mm each, along a laser chord of 95 mm. By summing a total of 30 laser pulses (0.6 J, 10 Hz), an observational error of 3% in n e and 6% in T e (at n e = 9.4 × 10 18 m −3 ) can be obtained. Single pulse Thomson scattering measurements can be performed with the same accuracy for n e > 2.8 × 10 20 m −3 . The minimum measurable density and temperature are n e < 1 × 10 17 m −3and T e < 0.07 eV, respectively. In addition, using the Rayleigh peak, superimposed on the Thomson scattered spectrum, the neutral density (n 0 ) of the plasma can be measured with an accuracy of 25% (at n 0 = 1 × 10 20 m −3 ). In this report, the performance of the Thomson scattering system will be shown along with unprecedented accurate Thomson-Rayleigh scattering measurements on a low-temperature argon plasma expansion into a low-pressure background.