A dimer of d-pinocarvone from Cedronella canariensis

Preparation of Campholenal Analogues: Chirons for the lipophilic moiety of sandalwood‐like odorant alcohols

“…I3C-NMR: Table 3. MS: 238 (0, M+'), 194 (68), 120 (94), 107 (loo), 91 (53), 79 (42), 67 (26), 59 (21), 55 (33), 41 (38).…”

“…Oxidation (pyridinium chlorochromate, CH2C12; 88 % yield) afforded (-)-2k ([a]g = -38.1 (c = 2.1, MeOH)) which was treated with a methyl Grignardreagent to give the tertiary alcohol (-)-9 (94% yield; a'," = -25.1) with the same absolute configuration as that obtained by a double addition of methyl Grignard reagent to (-)-21 [37] ([a]g = -24.4; 87% yield). The fact that oxidation (CrO,; 78% yield) of (+)-trans-pinocarveol ((+)-lo) (M'," = +53) gave (+)-pinocarvone (a'," = +52.7 (neat)) [38] and that (-)-2d (m'," = -26.3 (neat)) was also obtained from the hydride reduction (LiAIH4, 76 %) of tosylate (-)-7d, prepared from alcohol (-)-7b [39], confirms the absolute configuration of all compounds described in our work [40].…”

Composition of the Essential Oils ofCedronella canariensis(L.) Webb et Berth, ssp.canariensisand ssp.anisataf.glabraand f.pubescens

“…Only limited information is available on the chemical composition of Ceclronella (7)(8)(9). First results on the oil from both "varieties"were published by Engel et al (10,ll) followed by L6pez-Garcia et al (12) and Lawrence ( 1 3~4 ) .…”

Chemistry of South African Lamiaceae: Structures and Biological Activity of Terpenoids

“…Cedronella genus is represented by only one species in SA viz C. canariensis. The phytochemical studies of the aerial parts resulted in isolation of a dimer of d-pinocarvone (9), cedronellone (10), and ursolic acid (11) [17].…”