In this paper, X will denote a C ∞ manifold. In a very famous paper, Kontsevich [Ko] showed that the differential graded Lie algebra (DGLA) of polydifferential operators on X is formal. Calaque [C1] extended this theorem to any Lie algebroid. More precisely, given any Lie algebroid E over X, he defined the DGLA of E-polydifferential operators, Γ(X, E D * poly ), and showed that it is formal. Denote by Γ(X, E T * poly ) the DGLA of E-polyvector fields. Considering M , a module over E, we define Γ(X, E T * poly (M )) the Γ(X, E T * poly )-module of E-polyvector fields with values in M . Similarly, we define the Γ(X, E D * poly )-module of E-polydifferential operators with values in M , Γ(X, E D * poly (M )). We show that there is a quasi-isomorphism of L∞-modules over Γ(X, E T * poly ) from Γ(X, E T * poly (M )) to Γ(X, E D * poly (M )). Our result extends Calaque 's (and Kontsevich's) result.